Browse > Article

Separation of Gas Based on PTMSP-silica-PEI Composites  

Kang Tae-Bum (Department of Chemistry, Sang Myung University)
Hong Se-Lyung (Department of Chemistry, Sang Myung University)
Publication Information
Membrane Journal / v.16, no.2, 2006 , pp. 123-132 More about this Journal
Abstract
The PTMSP-silica-PEI composite membranes were synthesized from tetraethoxysilane (TEOS) and poly (1-trimethylsilyl-1-propyne) (PTMSP) by sol-gel process. The PTMSP-silica nanocomposite membranes were characterized by $^1H-NMR$, FT-IR, TGA, XPS, SEM, GPC and gas permeation measurements were accomplished with $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4$. The gases permeability increased with increasing TEOS content. Both the permeability and selectivity of $H_2,\;CH_4$ increased to 15 wt% TEOS. While the permeability of $O_2,\;CO_2$ increased without decrease of selectivity.
Keywords
PTMSP-silica-PEI; nanocomposite membrane; sol-gel; ideal separation factor;
Citations & Related Records
연도 인용수 순위
  • Reference
1 S. P. Nunes, K. V. Peinemann, K. Ohlrogge, A. Alpers, M. Keller, and A. T. N. Pires, 'Membranes of poly(ether imide) and nanodispersed silica', J. Membrane Sci., 157, 219 (1999)   DOI   ScienceOn
2 C. J. Cornelius and E. Marand, 'Hybrid silica-polyimide composite membranes : gas transport properties', J. Membrane Sci., 202, 97 (2002)   DOI   ScienceOn
3 H. B. Park, J. K. Kim, S. Y. Nam, and Y. M. Lee, 'Imide-siloxane block copolymer/silica hybrid membranes: preparation, characterization and gas separation properties', J. Membrane Sci., 220, 59 (2003)   DOI
4 M. Moaddeb and W. J. Koros, 'Gas transport properties of thin polymeric membranes in the presence of silicon dioxide particles', J. Membrane Sci., 125, 143 (1997)   DOI   ScienceOn
5 Q. Hu, E. Marand, S. Dhingra, D. Fritsch, J. Wen, and G. Wilkes, '$Poly(amide-imide)/TiO_2$ nanocomposite gas separation membranes: fabrication and characterization', J. Membrane Sci., 135, 65 (1997)   DOI   ScienceOn
6 S. P. Nunes, J. Schultz, and K. V. Peinemann, 'Silicone membranes with silica nanoparticles', J. Mater. Sci. Lett., 15, 1139 (1996)   DOI   ScienceOn
7 Z. He, I. Pinnau, and A. Morisato, 'Nanostructured poly(4-methyl-2-pentyne)/silica hybrid membranes for gas separation', Desalination, 146, 11 (2002)   DOI
8 T. C. Merkel, 'Organic-inorganic nanocomposite membranes for vapor separations', Ph.D. dissertation, North Carolina State University, USA (2001)
9 M. Jia, K. V. Peinemann, and R. D. Behling, 'Molecular sieving effect of the zeolite-filled silicone rubber membrane in gas separation', J. Membrane Sci., 57, 289 (1991)   DOI
10 M. Langsam, M. Anand, and E. J. Karwacki, 'Substituted propyne polymers I. Chemical surface modification of poly[1-( trimethylsily1)propyne) for gas separation membranes', Gas Separation & Purification, 2, 162 (1988)   DOI   ScienceOn
11 I. Pinnau and L. G. Toy, 'Transport of organic vapors through poly(1-trimethylsilyl-1-propyne)', J. Membrane Sci., 116, 199 (1996)   DOI   ScienceOn
12 Toshio Masuda, Yuichiro Iguchi, Ben-Zhong Tang, and Toshinobu Higashimura, 'Diffusion and solution of gases in substituted polyacetylene membranes', Polymer, 29, 2041 (1988)   DOI   ScienceOn
13 Yu Nagase, Yuriko Takamura, and Kiyohide Matsui, 'Chemical Modification of Poly (substituted-Acetylene). V. Alkylsilylation of Poly(1-Trimethylsilyl-1-Propyne) and Improved Liquid Separating Property at Pervaporation', J. Applied Polymer Sci., 42, 185 (1991)   DOI
14 T. C. Merkel, B. D. Freeman, R. J. Spontak, Z. He, I. Pinnau, P. Meakin, and A. J. Hill, 'Ultrapermeable reverse-selective nanocomposite membranes', Science, 296, 519 (2002)   DOI   ScienceOn
15 K. Nagai, A. Higuchi, and T. Nakagawa, 'Bromination and Gas Permeability of poly(1-trimethylsilyl-1-propyne) Membrane', J. Applied Polymer Sci., 54, 1207 (1994)   DOI   ScienceOn
16 Shun-He Zhong, Chuan-Feng Li, and Xiu-Fen Xiao, 'Preparation and characterization of polyimide-silica hybrid membranes on kieselguhr-mullite supports', J. Membrane Sci., 199, 53 (2002)   DOI
17 M. Adachi, Y. Suzuki, N. Kashiwagi, T. Isobe, and M. Senna, 'Preparation and properties of polymer microspheres dispersed in a silica gel film', Colloids Surfaces A: Physiochem. Eng. Aspects, 153, 617 (1998)
18 A. C. Savoca, A. D. Surnamer, and Chao-fong Tien, 'Gas Transport in poly(silylpropynes): The Chemical Structure Point of View', Macromolecules, 26, 6211 (1993)   DOI   ScienceOn
19 J. M. Watson and M. G. Baron, 'Precise static and dynamic permeation measurements using a continuous-flow vacuum cell', J. Membrane Sci., 106, 259 (1995)   DOI   ScienceOn
20 P. Winberg, K. Desitter, C. Dotremont, S. Mullens, I. F. J. Vankelecom, and F. H. J. Maurer, 'Free volume and interstitial mesopores in silica filled poly(1-trimethylsilyl-1-propyne) nanocomposites', Macromolecules, 38, 3776 (2005)   DOI   ScienceOn
21 T. C. Merkel, V. Bondar, K. Nagai, and B. D. Freeman, 'Sorption and Transport of Hydrocarbon and Perfluorocarbon Gases in Poly(1-trimethylsilyl-1-propyne)', J. Polymer Sci.: Part B: Polymer Physics., 38, 273 (2000)   DOI   ScienceOn
22 T. C. Merkel, Z. He, I. Pinnau, B. D. Freeman, P. Meakin, and A. J. Hill, 'Effect of nanoparticles on gas sorption and transport in poly(l-trimethylsilyl-l-propyne)', Macromolecules, 36, 6844 (2003)   DOI   ScienceOn
23 John F. Moulder, William F. Stickle, Peter E. Sobol, and Kenneth D. Bomben, Handbook of X-Ray Photoelectron Spectroscopy, (1992)
24 I. Pinnau and Z. He, Filled superglassy membrane, US Patent 6,316,684 B1 (2001)
25 Kazukiyo Nagai and Tsutomu Nakagawa, 'Effects of aging on the gas permeability and solubility in poly(1-trimethylsilyl-1-propyne) membranes synthesized with various catalysts', J. Membrane Sci., 105, 261 (1995)   DOI   ScienceOn
26 M. Langsam and L. M. Robeson, 'Substituted propyne polymers-Part II. Effects of aging on the gas permeability properties of poly[1-(trimethylsilyl) propyne] for gas separation membranes', Polymer Eng. Sci., 29(1), 44 (1989)   DOI   ScienceOn
27 K.Takada, H. Matsuya, T. Masuda, and T. Higashimura, 'Gas-permeability of polyacetylenes carrying substituents', J. Applied Polymer Sci., 30, 1605 (1985)   DOI   ScienceOn
28 C. Joly, S. Goizet, J. C. Schrotter, J. Sanchez, and M. Escoubes, 'Sol-gel polyimide-silica composite membrane : gas transport properties', J. Membrane Sci., 130, 63 (1997)   DOI
29 Yu Nagase, Tomoko Ueda, Kiyohide Matsui, and Masaki Uchikura, 'Chemical Modification of poly(substituted-acetylene). I. Synthesis and Gas Permeability of Poly(1-trimethylsilyl-1-propyne)/ Poly (dimethylsiloxane) Graft Copolymer', J. Polymer Sci.: Part B: Polymer Physics, 29, 171 (1991)   DOI
30 L. Starannikova, V. Khodzhaeva, and Yu. Yampolskii, 'Mechanism of aging of poly[1- (trimethylsilyl)-1-propyne] and its effect on gas permeability', J. Membrane Sci., 244, 183 (2004)   DOI
31 Kazukiyo Nagai, Toshio Masuda, Tsutomu Nakagawa, Benny D. Freeman, and Ingo Pinnau, 'Poly[1-(trimethylsilyl)-1-propyne] and related polymers: synthesis, properties and functions', Prog. Polym. Sci., 26, 721 (2001)   DOI   ScienceOn
32 T. Masuda, E. Isobe, and T. Higashimura, 'Polymerization of 1-(trimethylsilyl)-1-propyne by halides of niobium(V) and tantalum(V) and polymer properties', Macromolecules, 18, 841 (1985)   DOI
33 Kristien De Sitter, Petra Winberg, Jan D'Haen, Chris Dotremont, Roger Leysen, Johan A. Martens, Steven Mullens, Frans H. J. Maurer, and Ivo F. J. Vankelecom, 'Silica filled poly(1-trimethylsilyl-1-propyne) nanocomposite membrnae: Relation between the transport of gases and structural characteristics', J. Membrane Sci., 278, 83 (2006)   DOI
34 Dominique Gomes, Suzana P. Nunes, and Klaus-Viktor Peinemann, 'Membranes for gas separation based on poly(1-trimethylsilyl-1-propyne)-silica nanocomposites', J. Membrane Sci., 246, 13 (2005)   DOI   ScienceOn
35 T. B. Kang, H. K. Lee, and S. H. Cho, 'Separation of $H_2-N_2$ Gas Mixture by PTMSP-PEI and PDMS-PEI Composite Membranes', Membrane Journal, 13(4), 291 (2003)
36 J. M. Watson and P. A. Payne, 'A study of organic compound pervaporation through silicone rubber', J. Membrane Sci., 49, 171 (1990)   DOI   ScienceOn
37 R. M. Felder and G. S. Huvard, 'Permeation, diffusion and sorption of gases and vapors', in: R. A. Fava (Ed.), Methods of Experimental Physics (Polymers) 16, Academic Press, New York (1981)
38 T. C. Merkel, V. Bondar, K. Nagai, and B. D. Freeman, 'Sorption and Transport of Hydrocarbon and Perfluorocarbon Gases in Poly(1-trimethylsilyl-1-propyne)', J. Polymer Science: Part B: Polymer Physics, 38, 273 (2000)   DOI   ScienceOn