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1-Dimensional Zinc Polymer Containing the Quadruply Bridging Oxygen Ligand : $[Zn_4(1,3- BDC)_3({\mu}_4-O)\;(pyridine)_2]$  

Min Dongwon (Department of Chemistry(BK21), Sungkyunkwan University)
Lee Soon W. (Department of Chemistry(BK21), Sungkyunkwan University)
Publication Information
Korean Journal of Crystallography / v.15, no.2, 2004 , pp. 69-73 More about this Journal
Abstract
The hydro(solve)thermal reaction of zinc(II) nitrate $(Zn(NO_3)_2{\cdot}6H_2O)$ with $1,3-BDCH_2\;(1,3-BDC= 1,3-benzenedicarboxylate)$ in the presence of pyridine a gave 1-dimensional zinc polymer $[Zn(1,3- BDC)({\mu}_4-O)\;(pyridine)_2]$ (1). X-ray structure determination revealed that polymer 1 has a quadruply bridging oxygen $({\mu}_4-O)$ ligand. This polymer consists of two strands linked by 1,3-BDC ligands, and each strand is formed by connecting the monomer units by 1,3-DBC ligands.
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