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Synthesis and X-ray Crystal Structure of the Ethylenediammonium Monohydric Phosphate  

Tae-Sun Chang (Division of Advanced Technology, Korea Research Institute of Chemical Technology)
Chong-Hyeak Kim (Division of Advanced Technology, Korea Research Institute of Chemical Technology)
Deug-Hee Cho (Division of Advanced Technology, Korea Research Institute of Chemical Technology)
Dong-Koo Lee (Division of Advanced Technology, Korea Research Institute of Chemical Technology)
Tianyou Song (Department of Chemistry, Jilin University)
Publication Information
Korean Journal of Crystallography / v.13, no.2, 2002 , pp. 96-100 More about this Journal
Abstract
The title compound, (H/sub 3/NCH/sub 2/CH/sub 2/NH/sub 3/)HPO/sub 4/ (Ⅰ), has been synthesized by hydrothermal technique for the first time and its novel structure analyzed by X-ray single crystallography. The compound (Ⅰ) crystallizes in the monoclinic system, P2/sub 1//c space group with a＝10.209(1), b＝7.891(1), c＝ 8.039(1) (equation omitted), β＝ 92.138(9)°, V＝: 647.2(2) (equation omitted), Z＝4, R/sub 1/＝0.0295 and ωR/sub 2/＝0.0811 for 1141 independent reflections. The compound (Ⅰ) is interconnected to give a three-dimensional network through hydrogen-bonding interactions.
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