Browse > Article

Crystal Structure of Two-Dimensional Bis(isonicotinato)tet-raaquazinc(II) Complex Linked by Hydrogen-Bonds  

Park, Ki-Young (Department of Cultural Heritage Conservation Science, Kongju National University, Kongju 314-701)
Kim, Moon-Jip (Department of Physics, Soonchunhyang University, Asan 336-600)
Suh, Il-Hwan (Department of Physics, Chungnam National University, Taejon 305-764)
Publication Information
Korean Journal of Crystallography / v.13, no.1, 2002 , pp. 17-20 More about this Journal
Abstract
The complex [Zn(L)₂(H₂O)₄] (1) (L = isonicotinate) has been prepared and characterized by X-ray crystallography. Compound 1 crystallizes in the triclinic space group P1, with a = 6.9062(4) , b = 9.2618(7) , c = 6.3313(3) , α = 104.986(6)°, β = 112.865(4)°, γ = 96.213(6)°, V = 350.41(4) , Z = 1, R₁(wR₂) for 1225 observed reflections of [I > 2σ(I)] was 0.0209 (0.0591). The coordination environment of the zinc atom can be described as an octahedron in which the isonicotinato ligands are mutually trans. Compound 1 is also connected into a two-dimensional chain via hydrogen-bonds.
Keywords
Citations & Related Records
연도 인용수 순위
  • Reference
1 Miklos, D., Segla, P., Palicova, M., Kopcova, M., Melnik, M., Valko, M., Glowiak, T., Mrozinski, J. and Korabik, M., Polyhedron, 20, 1867 (2001)
2 Sheldrick, G. M., Acta Crystallogr., Sect. A., A46, 467 (1990)
3 Segla', P., Palicova, M., Koman, M., Miklos, D. and Melnik, M., Inorg. Chem. Commun., 3, 120 (2000)
4 Waizumi, K., Takuno, M., Fukushima, N. and Masuda, H., J. Coord. Chem., 44, 269 (1998)
5 Palicova, M., Segla, P., Miklos, D., Kopcova, M., Melnik, M., Dudova, B., Hudecova, D. and Glowiak, T., Polyhedron, 19, 2689 (2000)
6 Chapman, M. E., Ayyappan, P., Foxman, B. M., Yee, G. T. and Lin, W., Cryst. Growth Des., 1, 159 (2001)
7 Sheldrick, G. M., SHELXL-97, Program for the Refinement of Crystal Structures, University of G ttingen, Germany (1997)