Browse > Article
http://dx.doi.org/10.9766/KIMST.2013.16.5.690

Review : Ionic Liquids as Green Solvent  

Lee, Junwung (KISTI)
Publication Information
Journal of the Korea Institute of Military Science and Technology / v.16, no.5, 2013 , pp. 690-702 More about this Journal
Abstract
Ionic liquids(ILs) have been the most investigated chemicals among green solvents including water, glycerol, supercritical carbon dioxdie($scCO_2$). ILs are attracting organic as well as inorganic chemicals because most ionic liquids' vapor pressures are very low so that ILs are liquids phase at ambient conditions. ILs are composed of various anions and cations, thus chemists can design functionalized solvents and/or catalysts that can be used in specific synthetic reactions by means of combinations of different ions. Many scientists believe ILs being green materials because of its low vapor pressure as well as the flexibility in controlling the chemical and physical properties. In this review the author describes recent development of ILs focused on imidazolium and pyridinium ILs which are being most investigated presently. In order to apply this materials in industrial level, the toxicity matter must be resolved first. In this regard, the author describes recent research trend regarding environmental effects by ILs as well as some meaningful results as well.
Keywords
Ionic Liquids; Organic Synthesis; Inorganic Synthesis; Vapor Pressure; Anion; Cation; Toxicity; Green Solvent;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Lynd, L. R., Biotechnol. Bioeng., 105, 1, 2010.   DOI   ScienceOn
2 Tao, F. et al., ChemSusChem, 3, 1298, 2010.   DOI   ScienceOn
3 Ignatyev, I. A. et al., Green Chem., 12, 1790, 2010.   DOI   ScienceOn
4 Zhao, H. et al., Science, 316, 1597, 2007.   DOI   ScienceOn
5 Kamiya, N. et al., Biotechnol. Lett., 30, 1037, 2008.   DOI
6 Lee, S. H. et al., Biotechnol. Bioeng., 102, 1368, 2009.   DOI   ScienceOn
7 Le, Z. G. et al., J. Heterocycl. Chem., 43, 1123, 2006.   DOI
8 Aksin O. and Krause, N., Adv. Synth. Catal., 350, 1106, 2008.   DOI   ScienceOn
9 Gu, Y. L. et al., Adv. Synth. Catal., 347, 512, 2005.   DOI   ScienceOn
10 Forsyth, S. A. et al., Org. Process Res. Dev., 10, 94, 2006.   DOI   ScienceOn
11 Weng, J. Y. et al., Green Chem., 8, 96, 2006.   DOI   ScienceOn
12 Boon, J. A. et al., J. Org. Chem., 51, 480, 1986.   DOI
13 Deng, Y. Q. et al., US Patent, No. US-2011-0021810-A1, 2011.
14 Weitkamp J. and Traa, Y., Catal. Today, 49, 193, 1999.   DOI   ScienceOn
15 Ignatyev, I. A. et al., ChemSusChem, 3, 91, 2010.   DOI
16 Huang, C. et al., Appl. Catal., A, 277, 41, 2004.   DOI   ScienceOn
17 Song, C. et al., Chem. Commun., 1695, 2000.
18 Ladnak, V. et al., Adv. Synth. Catal., 349, 719, 2007.   DOI   ScienceOn
19 Freudenmann, D. et al., Angew. Chem. Int. Ed,. 50, 11050, 2011.   DOI   ScienceOn
20 Shamsipur, M. et al., J. Mol. Liq. 157, 43, 2010.   DOI   ScienceOn
21 Okrut, A. C. and Feldmann, Z. Anorg. Allg. Chem. 633, 2144, 2007.   DOI   ScienceOn
22 Sun, D. and Hughbanks, T., Inorg. Chem. 39, 1964, 2000.   DOI   ScienceOn
23 Sakamoto, H. et al., Inorg. Chem. 45, 4578, 2006.   DOI   ScienceOn
24 Ahmed, E. et al., Z. Anorg. Allg. Chem. 635, 297, 2009.   DOI   ScienceOn
25 Guloy, A. M. et al., Eur. J. Inorg. Chem. 2455, 2009.
26 Boros, E. et al., Chem. Commun. 46, 716, 2010.   DOI   ScienceOn
27 Cameron, T. S. et al., Chem. Eur. J. 8, 3386, 2002.   DOI
28 Wong, M. W. et al., Inorg. Chem., 44, 8908, 2005.   DOI   ScienceOn
29 Wolff, M. and Feldmann, C., Z. Anorg. Allg. Chem. 636, 1787, 2010.   DOI   ScienceOn
30 G. Santiso-QuiCones, G. et., Angew. Chem. Int. Ed., 48, 1133, 2009.   DOI   ScienceOn
31 Ahmed, E. et al., Z. Anorg. Allg. Chem. 636, 2602, 2010.   DOI   ScienceOn
32 Kim, D. W., C. E. Song and Chi, D. Y., J. Am. Chem. Soc. 124, 10278, 2002.   DOI   ScienceOn
33 M. Wolff, et al., Angew. Chem. Int. Ed., 50, 4970, 2011.   DOI   ScienceOn
34 Lu, J. Y., Coord. Chem. Rev. 246, 327, 2003.   DOI   ScienceOn
35 Liao, J. H. et al., Cryst. Growth Des., 6, 1062, 2006.   DOI   ScienceOn
36 Cooper, E. R. et al., Nature, 430, 1012, 2004.   DOI   ScienceOn
37 Dybtsev, D. et al., Chem. Commun., 1594, 2004.
38 Jin, K. et al., Chem. Commun., 2872, 2002.
39 Xu, L. et al., Chem. Commun., 3431, 2009.
40 Byrne, P. J., Dalton Trans. 795, 2005.
41 Wei, Y. et al., Angew. Chem. Int. Ed., 49, 5367, 2010.   DOI   ScienceOn
42 http://events.dechema.de/batil2.html; BATIL2, 2010 http://www.rsc.org/Publishing/Journals/gc/News/2010/BATIL2_2009.asp.
43 http://www.il-eco.uft.uni-bremen.de.
44 Davis, J. H. et al., Tetrahedron Lett., 39, 8955, 1998.   DOI   ScienceOn
45 Pernak, J. et al., Eur. J. Med. Chem., 36, 313, 2001.   DOI   ScienceOn
46 Ignatyev, I. A. et al., ChemSusChem, 3, 91, 2010.   DOI
47 Petkovic, M., et al., Chem. Soc. Rev., 40, 1383, 2011.   DOI   ScienceOn
48 Yang, Z. H. Food Technol. Biotechnol., 47, 62, 2009.
49 Petkovic, M. et al., Green Chem., 11, 889, 2009.   DOI   ScienceOn
50 Fayet C. and Gelas, J., Carbohydr. Res., 122, 59, 1983.   DOI   ScienceOn
51 Lansalot-Matras C. et al., Catal. Commun., 4, 517, 2003.   DOI   ScienceOn
52 Wells, A. S. and Coombe, V. T., Org. Process Res. Dev., 10, 794, 2006.   DOI   ScienceOn
53 Cho, C. W. et al., Green Chem., 10, 67, 2008.   DOI   ScienceOn
54 Stolte, S. et al., Green Chem., 9, 1170, 2007.   DOI   ScienceOn
55 Pernak, J. Green Chem., 5, 52, 2003.   DOI   ScienceOn
56 Jastorff, B. et al., Green Chem., 7, 362, 2005.   DOI   ScienceOn
57 Pernak J. and Branicka, M., J. Surfactants Deterg., 6, 119, 2003.   DOI
58 Hough-Troutman, W. L. et al., New J. Chem., 33, 26, 2009.   DOI   ScienceOn
59 Docherty K. M. and Kulpa, C. F., Green Chem., 7, 185, 2005.   DOI   ScienceOn
60 Matzke, M. et al., Chemosphere, 74, 568, 2009.   DOI   ScienceOn
61 Mrozik, W. et al., J. Soils Sediments, 9, 237, 2009.   DOI
62 Couling, D. J. et al., Green Chem., 8, 82, 2006.   DOI   ScienceOn
63 Schmidt, M. W. et al. J. Phys. Chem. A., 109, 7285, 2005.   DOI   ScienceOn
64 Torrecilla, J. S. et al., Green Chem., 12, 123, 2010.   DOI   ScienceOn
65 Palomar, J. et al., Phys. Chem. Chem. Phys., 12, 1991, 2010.   DOI   ScienceOn
66 Gao, H. et al. Chem. Rev. 111, 7377, 2011.   DOI   ScienceOn
67 Wang, R. et al., Inorg. Chem. 46, 932, 2007.   DOI   ScienceOn
68 Jiang, W. et al., J. Phys. Chem. B, 112, 3121, 2008.   DOI   ScienceOn
69 Carlson, P. J. et al., J. Phys. Chem. B., 116, 503, 2012.   DOI   ScienceOn
70 Fox, D. M. et al., Ind. Eng. Res., 47, 6327, 2008.   DOI   ScienceOn
71 Pogodina, N. V. et al., J. Phys. Chem. Lett. 2, 2571, 2011.   DOI   ScienceOn
72 이준웅, 한국군사과학기술학회지, 14, 246, 2011.
73 Jason P. Hallett and Tom Welton, Chem. Rev., 111, 3508, 2011.   DOI   ScienceOn
74 Burrel, A. K. et al., Green Chem., 9, 449, 2007.   DOI   ScienceOn
75 이준웅, 한국군사과학기술학회지, 13, 1153, 2010.
76 이준웅, 한국군사과학기술학회지, 15, 475, 2012.
77 Scurto, A. M. and Schleicher, J. C., Green Chem. 11, 694, 2009.   DOI   ScienceOn
78 Kagimoto, J. et al., Chem. Lett., 37, 1026, 2008.   DOI   ScienceOn
79 Fukumoto, K. et al., J. Am. Chem. Soc., 127, 2398, 2005.   DOI   ScienceOn
80 Cassol, C. C. et al., Adv. Synth. Catal., 348, 243, 2006.   DOI   ScienceOn
81 Maase, M. and Massonne, K., U.S. Pat. US 2006/0149074 A1.
82 Linder, T. and Sundermeyer, J., Chem. Commun. 2914, 2009.
83 Cole, A. C. et al., J. Am. Chem. Soc., 124, 5962, 2002.   DOI   ScienceOn
84 Zhang, S. et al., J. Phys. Chem. Ref. Data, 35, 1475, 2006.   DOI   ScienceOn
85 Varnek, A. et al., Chem. Inf. Model, 47, 1111, 2007.   DOI   ScienceOn
86 Yoshizawa, M.et al., J. Am. Chem. Soc., 125, 15411, 2003.   DOI   ScienceOn
87 Belieres, J.-P. et al., J. Phys. Chem. B, 111, 4926, 2007.   DOI   ScienceOn
88 Luo, H. et al., J. Phys., Chem. B, 113, 4181, 2009.   DOI   ScienceOn
89 Luo, H. et al., J. Phys., Chem. B, 113, 4181, 2009.   DOI   ScienceOn
90 Rinaldi R. and Schüth, F., Energy Environ. Sci., 2, 610, 2009.   DOI   ScienceOn
91 Suganuma, S. K. et al., J. Am. Chem. Soc., 130, 12787, 2008.   DOI   ScienceOn
92 Zhang, Q. et al., Green Chem., 13, 2619, 2011.   DOI   ScienceOn
93 Rinaldi, R. and Schüth, F., ChemSusChem, 2, 1096, 2009.   DOI
94 Xiang, Q. et al., Appl. Biochem. Biotechnol., 107, 505, 2003.   DOI
95 Li C. and Zhao, Z. K., Adv. Synth. Catal., 349, 1847, 2007.   DOI   ScienceOn
96 Vanoye, L. et al., Green Chem., 11, 390, 2009.   DOI   ScienceOn