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Advances synthesis process of TNAZ  

전용구 (국방과학연구소)
Publication Information
Journal of the Korea Institute of Military Science and Technology / v.6, no.1, 2003 , pp. 108-115 More about this Journal
Abstract
TNAZ is a high explosive material because it is a highly strained ring compound containing one nitramine and gem dinditro groups. 1-t-butyl-3-nitroazetidine which was used as an intermediate previously, which declined the overall yield in synthesizing TNAZ. We obtained 1-t-butyl-3-hydroxymethyl-3-nitroazetidine in 64% yield from advances process which was used in synthesis of 1-t-butyl-3-nitroazetidine. The reaction pathway, shortening of reaction time, together with improvement of yield were studied too. We have obtained TNAZ in 85% yield.
Keywords
High energy material; 1,3,3-Trinitroazetidine(TNAE); 1-t-Butylamino-3-chloro-2-propanol; 1-t-Butyl-3-hydroxyazetidine hydrochloride; 1-t-Butyl-3-methanesulfonyazetidine; 1-t-Butyl-3,3-dinitroazetidine; oxidative nitration; steam castable explosive; mesylation;
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