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http://dx.doi.org/10.5850/JKSCT.2009.33.12.2002

Examination of Berberine Dye using GC-MS after Selective Degradation Treatments  

Ahn, Cheun-Soon (Dept. of Fashion Industry, University of Incheon)
Publication Information
Journal of the Korean Society of Clothing and Textiles / v.33, no.12, 2009 , pp. 2002-2010 More about this Journal
Abstract
The degradation behavior of berberine is examined using GC-MS to select the fingerprint products that can be used to identify berberine dye in badly faded archaeological textiles. A total of $100^{\circ}C$ thermal and $H_2O_2/UV/O_2$ degradation systems were used to degrade berberine chloride 0.1% solution up to 408 hours. The samples were analyzed using the GC-MS. Dihydroberberine, 2-pteridinamine, 6,7-dimethyl-N-[(trimethylsilyl) oxy]-, and 8-methoxy-11-[3-methylbutyl]-11H-indolo[3,2-c]-quinoline, 5-oxide were detected as the major products of thermal degradation and identified as the fingerprint products for berberine dye at the early stage of degradation. Isobenzofuran-1,3-dione,4,5-dimethoxy-, 9H-fluorene,3,6-bis(2-hydroxyethyl)-,1,3-dioxolo[4,5-g]isoquinolin-5(6H)-one,7,8-dihydro-, and 3-tert-butyl-4-hydroxyanisole were detected as the major products generated by the $H_2O_2/UV/O_2$ degradation and identified as the fingerprint products for berberine dye under severe degradation conditions.
Keywords
Berberine; Degradation; Amur cork tree; GC-MS; Natural dye;
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Times Cited By KSCI : 2  (Citation Analysis)
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