Browse > Article

The Change of Interactions of Chitosan/Sodium Dodecyl Sulfate in the Presence of Electrolytes  

배현숙 (창원대학교 의류학과)
강인숙 (창원대학교 의류학과)
Publication Information
Journal of the Korean Society of Clothing and Textiles / v.27, no.5, 2003 , pp. 524-532 More about this Journal
Abstract
The change of interactions of anionic surfactants, sodium dodecyl sulfate(SDS) and sodium tetradecyl sulfate(575) in the presence of electrolytes, to the chitosan-based polyelectrolyte(sol＇n and gel phase) were studied. The chitosan gel used in this study were crosslinked with epichlorohydrin(ECH). Binding isotherms were determined by potentiometric technique using a surfactant ion selective solid-state electrode and the results were represented by using the sequence generating function(SGF) method. The results of binding isotherm were shown comparatively high cooperativity. The addition of electrolytes in the chitosan/SDS system resulted in a shift of the binding to higher free surfactant concentration because of screen effect by the electrolytes. Degree of binding of chitosan gel was higher than that of chitosan sol＇n. And also a conformational phase transition of the chitosan gel in the presence of electrolytes has been investigated.
Keywords
chitosan; sodium dodecyl sulfate; electrolyte; degree of binding;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 /
[ Aspinall,G.O. ] / The polysaccharides
2 Synthesis and Characteristics of Interpenetrating Polymer Network Hydrogel Composed of Chitosan and Poly(acrylic acid.) /
[ Lee,J.W.;Kim,S.Y.;Kim,S.S.;Lee,Y.M.;Lee,K.H.;Kim,S.J. ] / J. Appl. Polym. Sci.   ScienceOn
3 Anionic Surfactants in Physical Chemistry of Surfactant Action: Surfactant Science Series /
[ Robb,I.D.;Lucassen-Reynders,E.H(ed.) ] / Polymer/Surfactant Interactions
4 The Interaction Between Polyelectrolytes and Surfactants of Opposite Charge /
[ Wei,Y.C.;Hudson,S.M. ] / J. Macromol. Sci., Rev. Macromol. Chem. Phys.
5 Surfactant-Polyelectrolyte Interactions. 4. Surfactant Chain Length Dependence of the Binding of Alkylpyridinium Cations to Dextran Sulfate /
[ Malovikova,A.;Hayakawak.;Kwak,J.C.T. ] / J. Phys. Chem.
6 Phase Transition in Ionic Gels /
[ Tananka,T.;Fillmore,D.;Sun,S.;Nishio,I.;Swislow,G.;Shah,A. ] / Phys. Rev. Lett.
7 PolycationPolya ion Complexes: Preparation and Properties of Poly-(Vinylben-zyltrimethylammonium) Poly-(Styrenesulfonate) /
[ Michaels,A.S.;Miekka,R.G. ] / J. Phys. Chem.
8 Thermodynamics of High Polymer Solutions /
[ Flory,P.J. ] / J. Chem. Phys.
9 Surfactant-Polyelectrolyte Interactions. 1. Binding of DodecyItrimethylammonium ions by Sodium Dextran Sulfate and Sodium Poly(styrenesulfonate) in Aqueous Solution in the Presence of Sodium Chloride /
[ Hayakawa,K.;Kwak,J.C.T. ] / J. Phys. Chem.
10 Collapse of Gels and the Critical Endpoint /
[ Tanaka,T. ] / Phys. Rev. Lett.
11 Studies on Chitosan-induced Metachromasy. 1. Metachromatic behavior of Sodium 2`-hydroxy-1,1`azo-naphthalene-4-sulfonate in the presence of Chitosan /
[ Gummow,B.D.;Robert,G.A.F. ] / Makromol. Chem.
12 Binding of Sodium Dodecyl Surfate to a Polyelectrolytes Based on Chitosan /
[ Wei,Y.C.;Hudson,S.M. ] / Marcromolecules   ScienceOn
13 Theory of the Phase Transition between Helix and Random Coil in Polypeptide Chains /
[ Zimm,B.H.;Bragg,J.K. ] / J. Chem. Phys.
14 The Cooperative Binding Behavior of Sodium Dodecyl Sulfate to Crooslinked Chitosan Films /
[ Bae,H.S.;Hudson,S.M. ] / J. Polym. Sci., Part A, Polym. Chem   ScienceOn
15 Interactions between Polyelectrolyte Based on Crosslinked Chitosan and Amphoteric Surfactant /
[ Bae,H.S. ] / J. Korean Fiber Soc.   과학기술학회마을
16 /
[ Thalberg,K.;Stam,J.;van,Lindblad,C.;Almgern,M.;Lindbman,B. ] / J. Phys. Chem
17 Partition Functions of Linear-Chain Molecules /
[ Lifson,S. ] / J. Chem. Phys.
18 Highly Deacetylated Chitosan and Its Properties /
[ Mima,S.;Miya,M.;Iwamoto,R.;Yoshikawa,S. ] / J. Appl. Polym. Sci   ScienceOn
19 Study of Surfactant-Polyelectrolyte Interactions. Binding of Dodecyl-and Tetradecy Itrimethy lammonium Bromide by Some carboxylic Polyelectrolytes /
[ Hayakawa,K.;Santerre,J.P;Kwak,J.C.T. ] / Macromolecules
20 Limiting Laws and Counterion Condensation in Polyelectrolyte Solution. Ⅲ. An Analysis Based on the Ionic Solution Theory /
[ Manning,G.S. ] / J. Chem. Phys.
21 Solubilization Properties of Polymer-Surfactant Complexes /
[ Saito,S. ] / J. Colloid Interface Sci   ScienceOn
22 Cationic Surfactants in Physical Chemistry /
[ Hayakawa,K.;Kwak,J.C.T.;D.N.Rubingh(ed.);P.M.Holland(ed.) ] / Surfactant Science Series
23 Collapse of Polyelectrolyte Networks Induced by Their Interaction with Oppositely Charged Surfactants /
[ Khokhlov,A.R.;Kramarenko,E.;Yu. Makhaeva,E.E;Starodubtzev,S.G. ] / Macromolecules
24 Evidence for Formation of Block and Random Copolymers of N-Acetyl-D-Glucosamine an D-Glucosamine by Hetero and Homogeneous Hydrolyses /
[ Kurita,K.;Sannan,T.;Iwakura,Y. ] / Makromol. Chem
25 Crosslinking Chitosan Membranes for Pervaporation of Alcohol-Water Mixture /
[ Yisong,Y.;Wenjun,L.;Tongyin,Y. ] / Polymer Communications
26 Method of Forming a Crosslinked Chitosan polymer and Product Thereof /
[ Mayer,J.;Kaplan,D. ] / U.S. Patent, 5,015,293
27 Cooperative Binding to Linear Biopolymers. 2. Thermodynamic Analysis of the Proflavine-Poly(L-Glutamic Acid) System /
[ Schwarz,G.;Klose,S.;Balthasar,W. ] / Eur. J. Biochem   ScienceOn