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The Change of Interactions of Chitosan/Sodium Dodecyl Sulfate in the Presence of Electrolytes  

배현숙 (창원대학교 의류학과)
강인숙 (창원대학교 의류학과)
Publication Information
Journal of the Korean Society of Clothing and Textiles / v.27, no.5, 2003 , pp. 523-523 More about this Journal
Abstract
The change of interactions of anionic surfactants, sodium dodecyl sulfate(SDS) and sodium tetradecyl sulfate(575) in the presence of electrolytes, to the chitosan-based polyelectrolyte(sol＇n and gel phase) were studied. The chitosan gel used in this study were crosslinked with epichlorohydrin(ECH). Binding isotherms were determined by potentiometric technique using a surfactant ion selective solid-state electrode and the results were represented by using the sequence generating function(SGF) method. The results of binding isotherm were shown comparatively high cooperativity. The addition of electrolytes in the chitosan/SDS system resulted in a shift of the binding to higher free surfactant concentration because of screen effect by the electrolytes. Degree of binding of chitosan gel was higher than that of chitosan sol＇n. And also a conformational phase transition of the chitosan gel in the presence of electrolytes has been investigated.
Keywords
chitosan; sodium dodecyl sulfate; electrolyte; degree of binding;
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  • Reference
1 Interactions between Polyelectrolyte Based on Crosslinked Chitosan and Amphoteric Surfactant /
[ Bae,H.S. ] / J. Korean Fiber Soc.
2 Studies on Chitosan-induced Metachromasy. 1. Metachromatic behavior of Sodium 2`-hydroxy-1,1`azo-naphthalene-4-sulfonate in the presence of Chitosan /
[ Gummow,B.D.;Robert,G.A.F. ] / Makromol. Chem.
3 Cationic Surfactants in Physical Chemistry /
[ Hayakawa,K.;Kwak,J.C.T.;D.N.Rubingh(ed.);P.M.Holland(ed.) ] / Surfactant Science Series
4 Collapse of Polyelectrolyte Networks Induced by Their Interaction with Oppositely Charged Surfactants /
[ Khokhlov,A.R.;Kramarenko,E.;Yu. Makhaeva,E.E;Starodubtzev,S.G. ] / Macromolecules
5 Evidence for Formation of Block and Random Copolymers of N-Acetyl-D-Glucosamine an D-Glucosamine by Hetero and Homogeneous Hydrolyses /
[ Kurita,K.;Sannan,T.;Iwakura,Y. ] / Makromol. Chem
6 Surfactant-Polyelectrolyte Interactions. 4. Surfactant Chain Length Dependence of the Binding of Alkylpyridinium Cations to Dextran Sulfate /
[ Malovikova,A.;Hayakawak.;Kwak,J.C.T. ] / J. Phys. Chem.
7 Anionic Surfactants in Physical Chemistry of Surfactant Action: Surfactant Science Series /
[ Robb,I.D.;Lucassen-Reynders,E.H(ed.) ] / Polymer/Surfactant Interactions
8 Collapse of Gels and the Critical Endpoint /
[ Tanaka,T. ] / Phys. Rev. Lett.
9 Phase Transition in Ionic Gels /
[ Tananka,T.;Fillmore,D.;Sun,S.;Nishio,I.;Swislow,G.;Shah,A. ] / Phys. Rev. Lett.
10 /
[ Thalberg,K.;Stam,J.;van,Lindblad,C.;Almgern,M.;Lindbman,B. ] / J. Phys. Chem
11 The Interaction Between Polyelectrolytes and Surfactants of Opposite Charge /
[ Wei,Y.C.;Hudson,S.M. ] / J. Macromol. Sci., Rev. Macromol. Chem. Phys.
12 Study of Surfactant-Polyelectrolyte Interactions. Binding of Dodecyl-and Tetradecy Itrimethy lammonium Bromide by Some carboxylic Polyelectrolytes /
[ Hayakawa,K.;Santerre,J.P;Kwak,J.C.T. ] / Macromolecules
13 /
[ Aspinall,G.O. ] / The polysaccharides
14 Synthesis and Characteristics of Interpenetrating Polymer Network Hydrogel Composed of Chitosan and Poly(acrylic acid.) /
[ Lee,J.W.;Kim,S.Y.;Kim,S.S.;Lee,Y.M.;Lee,K.H.;Kim,S.J. ] / J. Appl. Polym. Sci.   ScienceOn
15 Solubilization Properties of Polymer-Surfactant Complexes /
[ Saito,S. ] / J. Colloid Interface Sci   ScienceOn
16 Limiting Laws and Counterion Condensation in Polyelectrolyte Solution. Ⅲ. An Analysis Based on the Ionic Solution Theory /
[ Manning,G.S. ] / J. Chem. Phys.
17 Thermodynamics of High Polymer Solutions /
[ Flory,P.J. ] / J. Chem. Phys.
18 Surfactant-Polyelectrolyte Interactions. 1. Binding of DodecyItrimethylammonium ions by Sodium Dextran Sulfate and Sodium Poly(styrenesulfonate) in Aqueous Solution in the Presence of Sodium Chloride /
[ Hayakawa,K.;Kwak,J.C.T. ] / J. Phys. Chem.
19 PolycationPolya ion Complexes: Preparation and Properties of Poly-(Vinylben-zyltrimethylammonium) Poly-(Styrenesulfonate) /
[ Michaels,A.S.;Miekka,R.G. ] / J. Phys. Chem.
20 Cooperative Binding to Linear Biopolymers. 2. Thermodynamic Analysis of the Proflavine-Poly(L-Glutamic Acid) System /
[ Schwarz,G.;Klose,S.;Balthasar,W. ] / Eur. J. Biochem   ScienceOn
21 Highly Deacetylated Chitosan and Its Properties /
[ Mima,S.;Miya,M.;Iwamoto,R.;Yoshikawa,S. ] / J. Appl. Polym. Sci   ScienceOn
22 Method of Forming a Crosslinked Chitosan polymer and Product Thereof /
[ Mayer,J.;Kaplan,D. ] / U.S. Patent, 5,015,293
23 Crosslinking Chitosan Membranes for Pervaporation of Alcohol-Water Mixture /
[ Yisong,Y.;Wenjun,L.;Tongyin,Y. ] / Polymer Communications
24 The Cooperative Binding Behavior of Sodium Dodecyl Sulfate to Crooslinked Chitosan Films /
[ Bae,H.S.;Hudson,S.M. ] / J. Polym. Sci., Part A, Polym. Chem   ScienceOn
25 Binding of Sodium Dodecyl Surfate to a Polyelectrolytes Based on Chitosan /
[ Wei,Y.C.;Hudson,S.M. ] / Marcromolecules   ScienceOn
26 Theory of the Phase Transition between Helix and Random Coil in Polypeptide Chains /
[ Zimm,B.H.;Bragg,J.K. ] / J. Chem. Phys.
27 Partition Functions of Linear-Chain Molecules /
[ Lifson,S. ] / J. Chem. Phys.