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Separation of Chromophoric Substance from Madder Plant under Different Extraction and Analytical Conditions  

S. Kay Obendorf (Dept. of Textiles and Apparel, Cornell University)
Publication Information
Journal of the Korean Society of Clothing and Textiles / v.27, no.11, 2003 , pp. 1350-1357 More about this Journal
Abstract
This research was aimed to establish the standard extraction and analytical procedures for examining the chromophoric substance in madder root with the ultimate goal of identifying the dyes in badly faded textiles of archaeological origin. The separation temperature of gas chromatography, pH and other extraction conditions were tested. The results were as follows: The suitable separation temperature for the GC cappillary column was 50∼305$^{\circ}C$, and methanol was a good GC solvent for both standard alizarin and madder extraction. The best extraction of madder was achieved by 90 min soaking in room temperature followed by filtration and the actual heat extraction procedure. The best pH for extracting alizarin was pH 3 and above pH 5 alizarin was not detectible. Only alizarin and no purpurin was found in the extraction of the currently used madder plant.
Keywords
madder; alizarin; GC-MS; extraction; archaeological textile;
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