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http://dx.doi.org/10.14478/ace.2020.1063

Enhancement of Manganese Removal Ability from Water Phase Using Biochar of Prinus densiflora Bark  

Kim, Min-Ji (Institute of Carbon Fusion Technology (InCFT), Chungnam National University)
Choi, Jung Hoon (H-Pluseco Co., Ltd)
Choi, Tae Ryeong (Department of Environment Safety System Engineering, Semyung University)
Choi, Suk Soon (Department of Environment Safety System Engineering, Semyung University)
Ha, Jeong Hyub (Department of Integrated Environmental Systems, Pyeongtaek University)
Lee, Young-Seak (Department of Chemical Engineering and Applied Chemistry, Chungnam National University)
Publication Information
Applied Chemistry for Engineering / v.31, no.5, 2020 , pp. 526-531 More about this Journal
Abstract
Manganese ions contained in water phase are acting as a toxic substance in the human body and also known to affect the nervous system. In particular, effective treatment technology is required since manganese removal is difficult due to its high solubility in a wide pH range. In this study, Prinus densiflora bark was chemically modified with hydrogen peroxide, and the modified adsorbent was used for removing manganese ions in an aqueous solution. The modified adsorbent showed high removal capacity of 82.1 and 56.2%, respectively, at conditions of 5 and 10 mg/L manganese ions. Also, the adsorption isotherm from the data was applied to the theoretical equation. As a result, the adsorption behavior of manganese ions was better suited to the Langmuir than Freundlich model, and it was also found from kinematics that the pseudo-second order kinetic model was more suitable. In addition, the changes of Gibbs free energy indicated that the adsorption reaction became more spontaneously with increasing temperature. Consequently, these experimental results may be used as a water treatment technology which can efficiently treat manganese ions contained in water.
Keywords
Manganese removal; Biochar of Prinus densiflora bark;
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