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http://dx.doi.org/10.14478/ace.2018.1112

One-pot Synthesis of Hydrous MnO2 Nanowires for Selective Oxidative Transformation of Furfuryl Alcohol  

Mobina, Irshad (Department Chemical Engineering, Kangwon National University)
Choi, Bong Gill (Department Chemical Engineering, Kangwon National University)
Kim, Jung Won (Department Chemical Engineering, Kangwon National University)
Publication Information
Applied Chemistry for Engineering / v.30, no.1, 2019 , pp. 49-53 More about this Journal
Abstract
Hydrous $MnO_2$ nanowires were easily synthesized by an one-pot synthesis with a simple hydrothermal method. As prepared hydrous $MnO_2$ nanowires were characterized with scanning emission microscopy (SEM), transmit emission microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET). They showed a good catalytic activity with the suitable nano-size of 4-5 nm and morphology. The furfuryl alcohol was selected as a substrate and the reaction was carried out in a toluene solvent at $100^{\circ}C$ under the atmospheric pressure of oxygen. The hydrous $MnO_2$ nanowire catalyst exhibited an excellent yield of furfural with the first-rate selectivity and conversion. The catalytic performance during recycle tests was also carried out and the catalyst showed a good mechanical strength with a negligible loss in the activity over five reaction cycles.
Keywords
One-pot synthesis; Hydrous $MnO_2$ nanowires; Furfuryl alcohol; Furfural;
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