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http://dx.doi.org/10.14478/ace.2018.1066

Synthesis and Property Evaluation of Cationic Gemini Surfactants Using 1,4-Butanediol  

Kim, Kyung-Sil (Department of Engineering Chemistry, Chungbuk National Universicty)
Park, Jong-Kwon (Department of Engineering Chemistry, Chungbuk National Universicty)
Cho, Jung-Eun (Department of Engineering Chemistry, Chungbuk National Universicty)
Shin, Hye-Lin (Department of Engineering Chemistry, Chungbuk National Universicty)
Jeong, Noh-Hee (Department of Engineering Chemistry, Chungbuk National Universicty)
Publication Information
Applied Chemistry for Engineering / v.30, no.1, 2019 , pp. 17-22 More about this Journal
Abstract
In this study, cationic gemini surfactants were synthesized by increasing the length of the hydrophobic chain and using 1,4-butanediol as a spacer, and the result was confirmed by $^1H-NMR$. The synthesized surfactant was a white powder, and Kraffts point was below $0^{\circ}C$. Surface tension measurements revealed that the evaluated critical micelle concentration (c.m.c) was $1.8{\times}10^{-3}{\sim}6.5{\times}10^{-4}mol/L$ with a surface tension of 22.5~26.1 dyne/cm at the c.m.c. The initial foam height for CG 14-6E-14 estimated by Ross-Miles method was 16 cm and after 5 minutes the height was 14 cm. It was confirmed that the initial foam force and foam stability were the highest. The foam test and emulsion stability of synthesized gemini cationic surfactants were also compared to those of cetyltrimethylammonium bromide (CTAB), a commoly used surfactant.
Keywords
Cationic surfactant; Gemini surfactant; 1,4-Butanediol; Acyl chloride;
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