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http://dx.doi.org/10.14478/ace.2016.1106

Efficient Oxidative Scission of Alkenes or Alkynes with Heterogeneous Ruthenium Zirconia Catalyst  

Irshad, Mobina (Department Chemical Engineering, Kangwon National University)
Choi, Bong Gill (Department Chemical Engineering, Kangwon National University)
Kang, Onyu (Department Chemical Engineering, Kangwon National University)
Hong, Seok Bok (Department Chemical Engineering, Kangwon National University)
Hwang, Sung Yeon (Korea Research Institute of Chemical Technology)
Heo, Young Min (SKC Advanced Technology R&D Center)
Kim, Jung Won (Department Chemical Engineering, Kangwon National University)
Publication Information
Applied Chemistry for Engineering / v.27, no.6, 2016 , pp. 659-663 More about this Journal
Abstract
The efficiency of a heterogeneous ruthenium zirconia catalyst ($Ru(OH)_x/ZrO_2$) was demonstrated to the selective oxidative transformation of alkenes or alkynes. The scissions of C-C double bonds to aldehydes and triple bonds to diketones or carboxylic acids were carried out with (diacetoxyiodo)benzene as an oxidant under dichloromethane (5 mL)/water (0.5 mL) solvent system at $30^{\circ}C$ for wide range of substrates. The $Ru(OH)_x/ZrO_2$composite showed higher catalytic activity and selectivity than other ruthenium-based homogeneous or heterogeneous catalysts for the scission reaction. The catalyst exhibited a high mechanical stability, and no leaching of the metal was observed during the reaction. These features ensured the reusability of the catalyst for several times for the oxidative cleavage of unsaturated hydrocarbons.
Keywords
heterogeneous; ruthenium zirconia catalyst; alkenes or alkynes; scission; reusability;
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