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http://dx.doi.org/10.14478/ace.2015.1016

A Study on the Highly Effective Treatment of Spent Electroless Nickel Plating Solution by an Advanced Oxidation Process  

Seo, Minhye (Advanced Materials & Processing Center, Institute for Advanced Engineering)
Cho, Sungsu (Advanced Materials & Processing Center, Institute for Advanced Engineering)
Lee, Sooyoung (Advanced Materials & Processing Center, Institute for Advanced Engineering)
Kim, Jinho (Inchoen Chemical Co., LTD.)
Kang, Yong-Ho (Inchoen Chemical Co., LTD.)
Uhm, Sunghyun (Advanced Materials & Processing Center, Institute for Advanced Engineering)
Publication Information
Applied Chemistry for Engineering / v.26, no.3, 2015 , pp. 270-274 More about this Journal
Abstract
We develop advanced oxidation processes for the treatment of spent electroless nickel plating solution. Apart form recovering nickel by leaching and enrichment, more emphasis is placed on rendering the waste water recyclable via oxidizing phosphite and hypophosphite into phosphate which can then be precipitated easily. $UV/H_2O_2$ process is employed and the conversion efficiency of COD and $PO_4-P$, and $H_2O_2$ consumption are analyzed. Furthermore, the $UV/H_2O_2/O_3$ process in conjunction with $O_3$ generator enables us to not only save the treatment time by 6 hours but also reduce $H_2O_2$ consumption by 30%.
Keywords
spent electroless nickel plating solution; advanced oxidation process; photo-chemical method; chemical oxygen demand; phosphate;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 W. C. Ying, R. R. Bonk, and M. E. Tucker, Precipitation treatment of spent electroless nickel plating baths, J. Hazard. Mater., 18, 69-89 (1988).   DOI   ScienceOn
2 D. H. Cheng, W. Y. Xu, Z. Y. Zhang, and Z. H. Yiao, Electroless copper plating using hypophosphite as reducing agent, Met. Finish., 95, 34-37 (1997).
3 H-Y. Lee, Recovery of nickel from electroless plating wastewater by electrolysis method, J. Kor. Inst. Resour. Recycl., 21, 41-46 (2012).
4 L. E. de-Bashan and Y. Bashan, Recent advances in removing phosphorous from waste water and its future use as fertilizer (1997-2003), Water Res., 38, 4222-4246 (2004).   DOI   ScienceOn
5 E. Neyens and J. Baeyens, A review of classic Fenton's peroxidation as an advanced oxidation technique, J. Hazard. Mater., 98, 33-50 (2003).   DOI   ScienceOn
6 A. D. Bokare and W. Choi, Review of iron-free fenton-like systems for activating $H_2O_2$ in advanced oxidation processes, J. Hazard. Mater., 275, 121-135 (2014).   DOI   ScienceOn
7 D. S. Bhatkhande, V. G. Pangarkar, and A. A. C. M. Beenackers, Photocatalytic degradation for environmental applications, J. Chem. Technol. Biotechnol., 77, 102-116 (2002).   DOI   ScienceOn
8 P. R. Gogate and A. B. Pandit, A review of imperative technologies for waste water treatment I: oxidation technologies at ambient conditions, Adv. Environ. Res., 8, 501-551 (2004).   DOI   ScienceOn
9 C. Comninellis, A. Kapalka, S. Malato, S. A. Parsons, I. Poulios, and D. Mantzavinos, Advanced oxidation processes for water treatment: advances and trends for R&D, J. Chem. Technol. Biotechnol., 83, 769-776 (2008).   DOI   ScienceOn
10 J. M. Poyatos, M. M. Munio, M. C. Almecija, J. C. Torres, E. Hontoria, and F. Osorio, Advanced oxidation processes for wastewater treatment: state of the art, Water Air Soil Pollut., 205, 187-204 (2010).   DOI
11 J. Pawlat, H. D. Stryczewska, and K. Ebihara, Sterilization techniques for soil remediation and agriculture based on ozone and AOP, J. Adv. Oxid. Technol., 13, 138-145 (2010).
12 F. A. Al Momani, Potential use of solar energy for waste activated sludge treatment, Int. J. Sust. Eng., 6, 82-91 (2013).   DOI
13 C. Domeno, A. Rodriguez-Lafuente, J. Martos, R. Bilbao, and C. Nerin, VOC removal and deodorization of effluent gases from an industrial plant by photo-oxidation, chemical oxidation and ozonization, Environ. Sci. Technol., 44, 2585-2591 (2010).   DOI   ScienceOn
14 R. Sapach and T. Viraraghavan, An introduction to the use of hydrogen peroxide and ultraviolet radiation: An advanced oxidation process, J. Environ. Sci. Health, A., 32, 2355-2366 (1997).
15 P. Liu, C. Li, X. Liang, G. Lu, J. Xu, X. Dong, W. Zhang, and F. Ji, Recovery of high purity ferric phosphate from a spent electroless nickel plating bath, Green Chem., 16, 1217-1224 (2014).   DOI
16 S. Vilhunen, M. Vilve, M. Vepsalainen, and M. Sillanpaa, Removal of organic matter from a variety of water matrices by UV photolysis and UV/$H_2O_2$ method, J. Hazard. Mater., 179, 776-782 (2010).   DOI   ScienceOn
17 P. Liu, C. Li, X. Liang, J. Xu, G. Lu, and F. Ji, Advanced oxidation of hypophosphite and phosphite using a UV/$H_2O_2$ process, Environ. Technol., 34, 2231-2239 (2013).   DOI   ScienceOn
18 Y.-J. Shih, C.-P. Lin, and Y.-H. Huang, Application of fered-fenton and chemical precipitation process for the treatment of electroless nickel plating wastewater, Sep. Purif. Technol., 104, 100-105 (2013).   DOI   ScienceOn