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http://dx.doi.org/10.14478/ace.2014.1124

Synthesis of Phospholene Oxide Catalysts for Hydrolysis Stabilizers  

Lee, Jin-Ha (Department of Environmental Engineering, Kongju National University)
Lee, Chang-Young (Department of Environmental Engineering, Kongju National University)
Publication Information
Applied Chemistry for Engineering / v.26, no.1, 2015 , pp. 86-91 More about this Journal
Abstract
The MPPO (3-methyl-1-phenyl-2-phospholene-1-oxide) was prepared by using various polymerization inhibitors such as BHT (2,6-di-tert-butyl-4-methylphenol), TBC (4-tert-butylcatechol), and copper stearate. The MPPO was confirmed by the analysis using FTIR, $^1H$-NMR, and GC/MS regardless of the type of inhibitors. The yield of MPPO increased with the increase of reaction time, whereas the purity of MPPO decreased slightly. The yield and purity of MPPO increased with temperature, but the MPPO prepared by using copper stearate as a polymerization inhibitor exhibited no changes in the purity. The amount of inhibitors had no effect on the yield of MPPO. The purity of MPPOs increased with the amount of inhibitors, but the MPPO prepared by using BHT showed no changes of the purity. We found that the MPPO prepared by using copper stearate exhibited the highest catalytic activity for diphenylcarbodiimide synthesis.
Keywords
Phospholene oxide; Carbodiimides; Hydrolysis stabilizer; Polymerization inhibitors;
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