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The Syntheses of Phthalocyanine Hybrid Derivatives and Their Properties  

Kim, Seong Jin (Department of Industrial & Engineering Chemistry, Pukyoung National University)
An, Ba Ryong (Department of Industrial & Engineering Chemistry, Pukyoung National University)
Lee, Gun-Dae (Department of Industrial & Engineering Chemistry, Pukyoung National University)
Park, Seong Soo (Department of Industrial & Engineering Chemistry, Pukyoung National University)
Publication Information
Applied Chemistry for Engineering / v.24, no.3, 2013 , pp. 266-273 More about this Journal
Abstract
Phthalocyanine (Pc), porphyrin, subphthalocyanine, and perylene compounds can be applicable to the fields of optical storage media, organic solar cell, LCD, PDP, semiconductor, and counterfeit money detection etc. In this study, phthalocyanine hybrid derivatives were synthesized by cross-linking perylene, subphthalocyanine, or porphyrin to the main frame of Pc. Absorbtion band of two different wavelengths appeared simultaneously in the phthalocyanine hybrid derivatives. Compared to phthalocyanine, the solubility was enhanced and the degree of Q-band shift was changed according to the kind of substitute compounds. The chemical and optical properties of samples were analyzed using FT-IR, $^1H-NMR$, and UV-Vis spectroscopic techniques.
Keywords
phthalocyanine; subphthalocyanine; porphyrin; hybrid; solubility;
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