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Study on the Condensation Reaction of Alkyl Glycidyl Ethers and Fatty Acids  

Kim, Ji-Hyun (Department of Fine Chemical Engineering and Chemistry, BK21-E2M, Chungnam National University)
Hwang, Hyun Ah (Department of Green Chemistry and Environmental Biotechnology, University of Science & Technology)
Lee, Young-Seak (Department of Fine Chemical Engineering and Chemistry, BK21-E2M, Chungnam National University)
Lee, Byung Min (Environment and Resources Research Center, Korea Research Institute of Chemical Technology)
Publication Information
Applied Chemistry for Engineering / v.23, no.4, 2012 , pp. 416-420 More about this Journal
Abstract
A convenient procedure for the synthesis of fatty acid diesters was studied. Long chain diesters have been used as biolubricant and transformer oils. The series of octyl, dodecyl, hexadecyl, octadecyl, and octadec-9-enyl glycidyl ether were used to synthesize those diesters. Alkyl glycidyl ethers were reacted with fatty acid such as oleic acid and octanoic acid, and octanoic acid. The one-step / two-step reactions were compared during the condensation reaction. The products were confirmed by $^{1}H-NMR$, FT-IR, and HR/MS spectra. The yield of the product 1-O-acyl-2-O, 3-O-dioctadec-9-enoylglycerol was 55~60%.
Keywords
transformer oil; fatty acid; alkyl glycidyl ether; diester; condensation reaction;
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