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http://dx.doi.org/10.14478/ace.2011.22.6.697

Adsorption Characteristics of Uranium (VI) Ion on OenNdien Resin with Styrene Hazardous Material  

Kim, Joon-Tae (Department of Chemistry, Chosun University)
Publication Information
Applied Chemistry for Engineering / v.22, no.6, 2011 , pp. 697-702 More about this Journal
Abstract
Ion exchange resins have been synthesized from chloromethylated styrene-1,4-divinylbenzene (DVB) with 1%, 2%, 5% and 15%-crosslinkage and macrocyclic ligand of $OenNdien-H_4$ by copolymerization. The adsorption characteristics of uranium (${UO_2}^{2+}$), potassium ($K^+$) and neodymium ($Nd^{3+}$) metallic ions have been investigated. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, and crosslinkage on adsorption of metallic ions were also studied. The uranium ion showed the fast adsorption on the resins above pH 3. The optimum equilibrium time for the adsorption of metallic ions was about two hours. The adsorption selectivity determined in methanol solution was in increasing order uranium (${UO_2}^{2+}$) > potassium ($K^+$) > neodymium ($Nd^{3+}$) ion. Moreover, the adsorption was increased with the crosslinkage concentration in order of 1%, 2%, 5% and 15%-crosslinkage resin.
Keywords
styrene; divinylbenzene; crosslinkage; macrocyclic ligand; $OenNdien-H_4$;
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1 K. W. Chi, Y. S. Ahn, K. T. Shim, H. Huh, and J. S. Ahn, Bull. Kor. Chem. Soc., 23, 688 (2002).   DOI   ScienceOn
2 H. K. Frensddorff, J. Am. Chem. Soc., 93, 4684 (1971).   DOI
3 L. F. Lindoy, P. G. Grimslery, H. C. Lip, R. J. Smith, and J. T. Baker, Aust. J. Chem., 30, 2095 (1977).   DOI
4 L. F. Lindoy, K. R. Adam, D. S. Bladwine, A. Bashall, M. McPartlin, and H. R. Powell, J. Chem. Soc., Dalton Trans., 237 (1994).
5 M. A. Ahearn, J. Kim, A. J. Leong, L. F. Lindoy, G. V. Meehan, and O. A. Mattews, J. Chem. Soc., Dalton Trans., 3591 (1976).
6 K. S. Huh and S. G. Sin, Appl. Chem. Eng., 9, 680 (1998).
7 K. H. Park, Y. D. Kwon, Y. J. Chung, and E. K. Jang, Appl. Chem. Eng., 15, 106 (2004).
8 H. D. Jeong, D. S. Kim, and K. I. Kim, Appl. Chem. Eng., 16, 123 (2005).
9 G. Bombieri and G. Depaoli, Inorg. Chem. Acta., 18, 123 (1976).
10 T. Hayashita, J. H. Lee, S. Chem, and R. A. Bartsch, Anal. Chem., 63, 1844 (1991).   DOI
11 E. Blasius and K. P. Janzen, Pure Appl. Chem., 54, 2115 (1982).   DOI
12 C. W. Park, Industry an engineer of hazardous materials, Namyang Munhwa, Seoul, 3-92 (2007).
13 H. Egawa, T. Nonaka, and M. Ikari, J. Appl. Poly. Sci., 29, 2045 (1984).   DOI   ScienceOn
14 J. T. Kim, Appl. Chem. Eng., 20, 165 (2009).
15 S. M. Howdle, K. Jerabek, V. Leocorbo, P. C. Marr, and D. C. Sherrington, Polymer, 41, 7272 (2000).
16 R. C. Weast, Handbook of chemistry and physics, 70th, D52, CRC Press, New York (1989).
17 C. J. Pederson, J. Am. Chem. Soc., 92, 386 (1970).   DOI