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http://dx.doi.org/10.14478/ace.2011.22.6.587

Green Catalysts for Isobutane Alkylation Process  

Yoo, Kye Sang (Department of Chemical Engineering, Seoul National University of Science & Technology)
Publication Information
Applied Chemistry for Engineering / v.22, no.6, 2011 , pp. 587-593 More about this Journal
Abstract
As a result of increasing environmental concerns related to air quality and maintenance of automobiles, the alkylation of isobutane with olefins has become an even more important process for production of high quality gasoline. However, the widespread use of the alkylation process is limited by the polluting and corrosive liquid acid catalysts (HF and $H_2SO_4$) currently used in industry. For the reason, a large number of solid catalysts, especially zeolites, have been studied as an environmental friendly catalyst in this process. Recently, mesoporous solid acids and ionic liquids have been investigated as a green catalyst. In this review, the research of environmental friendly catalysts for an isobutane alkylation is summarized.
Keywords
isobutane alkylation; zeolites; ionic liquids; mesoporous solid acids;
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  • Reference
1 L. F. Albright, Alkylations Industrial. In Encyclopedia of Catalysis, ed. I. T. Horvath, 1, 191, John Wiley and Sons, New York (2003).
2 M. Radler, Oil Gas J., 95, 41 (1997).
3 EPA, Clean Air Act Amendments of 1990. Detailed Summary of Titles (1990)
4 A. Corma and A. Martinez, Catal. Rev. Sci. Eng., 35, 484 (1993).
5 W. R. Hartley, A. J. Englande Jr, and D. J. Harrington, Water Sci. Technol., 39, 305 (1999).   DOI   ScienceOn
6 N. Y. Kado, P. A. Kuzmicky, G. Loarca-Pina, and M. M. Mumtaz, Mutation Res., 412, 131 (1998).   DOI   ScienceOn
7 S. Vainiotalo, K. Pakari, and A. Aitio, Int. Arch. Environ. Occup. Health., 71, 391 (1998).   DOI   ScienceOn
8 G. H. Unzelman, Fuel Reformul., 11, 37 (1993).
9 L. F. Albright and K. V. Wood, Ind. Eng. Chem. Res., 36, 2110 (1997).   DOI   ScienceOn
10 J. Scherzer, Catal. Rev. Sci. Eng., 31, 215 (1989).   DOI
11 M. Radler, Oil Gas J., 95, 57 (1997).
12 F. Cardona, N. S. Gnep, M. Guisnet, G. Szabo, and P. Nascimento, Appl. Catal., A, 128, 243 (1995).   DOI   ScienceOn
13 M. F. Simpson, J. Wei, and S. Sundaresan, Ind. Eng. Chem. Res., 35, 3861 (1996).   DOI   ScienceOn
14 A. Corma, A. Martinez, and C. Martinez, J. Catal., 146, 185 (1994).   DOI   ScienceOn
15 C. Flego, I. Kiricsi, W. O. Parker, and M. G. Clerici, Appl. Catal., A, 124, 107 (1995).   DOI   ScienceOn
16 M. Stocker, H. Mostad, and T. Rorvik, Catal. Lett., 28, 203 (1994).   DOI   ScienceOn
17 C. Flego, L. Galasso, I. Kiricsi, and M. G. Clerici, Stud. Surf. Sci. Catal., 88, 585 (1994).
18 J. Weitkamp, Stud. Surf. Sci. Catal., 5, 65 (1980).
19 A. Corma, A. Martinez, and C. Martinez, Appl. Catal., A, 134, 169 (1996).   DOI   ScienceOn
20 M. Simpson, J. Wei, and S. Sundaresan, Ind. Eng. Chem. Res., 35, 3861 (1996).   DOI   ScienceOn
21 T. Rorvik, H. Mostad, O. H. Ellestad, and M. Stocker, Appl. Catal., A, 137, 235 (1996).   DOI   ScienceOn
22 K. P. De Jong, C. M. A. M. Mesters, D. G. R. Peferoen, P. T. M. Van Brugge, and C. De Groot, Chem. Eng. Sci., 51, 2053 (1996).   DOI   ScienceOn
23 C. A. Querini and E. Roa, Appl. Catal., A, 163, 199 (1997).   DOI   ScienceOn
24 A. Feller, A. Guzman, I. Zuazo, and J. A. Lercher, J. Catal., 224, 80 (2004).   DOI   ScienceOn
25 R. Josl, R. Klingmann, Y. Traa, R. Gläser, and J. Weitkamp, Catal. Commun., 5, 239 (2004).   DOI   ScienceOn
26 C. Sievers, I. Zuazo, A. Guzman, R. Olindo, H. Syska, and J. A. Lercher, J. Catal., 246, 315 (2007).   DOI   ScienceOn
27 A. Guzman, I. Zuazo, A. Feller, R. Olindo, C. Sievers, and J. A. Lercher, Micropor. Mesopor. Mater., 97, 49 (2006).   DOI   ScienceOn
28 S. Unverricht, S. Ernst, and J. Weitkamp, Stud. Surf. Sci. Catal., 84, 1693 (1994).
29 C. Sievers, J. S. Liebert, M. M. Stratmann, R. Olindo, and J. A. Lercher, Appl. Catal., A, 336, 89 (2008).   DOI   ScienceOn
30 A. Corma, A. Martinez, and C. Martinez, Catal. Lett., 28, 187 (1994).   DOI
31 K. Yoo and P. G. Smirniotis, Appl. Catal., A, 227, 171 (2002).   DOI   ScienceOn
32 A. Corma, V. Gomez, and A. Martinez, Appl. Catal., A, 119, 83 (1994).   DOI   ScienceOn
33 G. S. Nivarthy, Y. He, K. Seshan, and J. A. Lercher, J. Catal., 176, 192 (1998).   DOI   ScienceOn
34 R. Loenders, P. A. Jacobs, and J. A. Martens, J. Catal., 176, 545 (1998).   DOI   ScienceOn
35 A. Corma, A. Martinez, P. A. Arroyo, J. L. F. Monteiro, and E. F. Sousa-Aguiar, Appl. Catal., A, 142, 139 (1996).   DOI   ScienceOn
36 G. S. Nivarthy, K. Seshan, and J. A. Lercher, Micropor. Mesopor. Mater., 22, 379 (1998).   DOI   ScienceOn
37 K. Yoo, E. C. Burckle, and P. G. Smirniotis, Catal. Lett., 74, 85 (2001).   DOI   ScienceOn
38 J. Weitkamp and Y. Traa, Catal. Today, 49, 193 (1999).   DOI   ScienceOn
39 J. Weitkamp, Proc. 5th Intern. Zeolite Confer., eds. L. V. C. Rees, 858, London, United Kingdom (1980).
40 J. Weitkamp and S. Ernst, Proc. 13th World Pet. Congr., 3, 315, New York (1992).
41 A. E. Koklin, V. M. K. Chan, V. B. Kazanskii, and V. I. Bogdan, Kinet. Catal., 51, 410 (2010).   DOI   ScienceOn
42 D. N. Thompson, D. M. Ginosar, and K. C. Burch, Appl. Catal., A, 279, 109 (2005).   DOI   ScienceOn
43 D. M. Ginosar, D. N. Thompson, and K. C. Burch, Ind. Eng. Chem. Res., 45, 567 (2006).   DOI   ScienceOn
44 V. I. Bogdan and V. B. Kazanskii, Kinet. Catal., 46, 834 (2005).   DOI   ScienceOn
45 D. N. Thompson, D. M. Ginosar, and K. C. Burch, Ind. Eng. Chem. Res., 44, 4534 (2005).   DOI   ScienceOn
46 G. M. Santana and A. Akgerman, Ind. Eng. Chem. Res., 40, 3879 (2001).   DOI   ScienceOn
47 K. Yoo and P. G. Smirniotis, Ind. Eng. Chem. Res., 44, 85 (2005).   DOI   ScienceOn
48 T. Blasco, A. Corma, A. Martínez, and P. Martínez-Escolano, J. Catal., 177, 306 (1998).   DOI   ScienceOn
49 Z. Zhang, Y. Han, F. S. Xiao, S. Qiu, L. Zhu, R. Wang, Y. Yu, Z. Zhang, B. Zou, Y. Wang, H. Sun, D. Zhao, and Y. Wei, J. Am. Chem. Soc., 123, 5014 (2001).   DOI   ScienceOn
50 W. Dong, and B. H. Chen, Petrochem. Technol., 31, 84 (2002).
51 E. I. Basaldella, M. S. Legnoverde, I. Jimenez-Morales, E. Rodriguez-Castellon, B. O. Dalla Costa, and C. A. Querini, Adsorption., 17, 631 (2011).   DOI   ScienceOn
52 W. Shen, D. Dubé, and S. Kaliaguine, Catal. Commun., 10, 291 (2008).   DOI   ScienceOn
53 J. Dupont, R. F. de Souza, and P. A. Z. Suarez, Chem. Rev., 102, 3667 (2002).   DOI   ScienceOn
54 W. Shen, Y. Gu, H. Xu, R. Che, D. Dube, and S. Kaliaguine, Appl. Catal., A, 377, 1 (2010).   DOI   ScienceOn
55 W. Shen, Y. Gu, H. Xu, R. Che, D. Dubé, and S. Kaliaguine, Ind. Eng. Chem. Res., 49, 7201 (2010).   DOI   ScienceOn
56 T. Welton, Chem. Rev., 99, 2071 (1999).   DOI   ScienceOn
57 D. B. Zhao, M. Wu, Y. Kou, and E. Z. Min, Catal. Today., 74, 157 (2002).   DOI   ScienceOn
58 T. Welton, Coord. Chem. Rev., 248, 2459 (2004).   DOI   ScienceOn
59 V. I. Parvulescu and C. Hardacre, Chem. Rev., 107, 2615 (2007).   DOI   ScienceOn
60 P. Wasserscheid and T. Welton, Ionic Liquids in Synthesis, Wiley-VCH, Weinheim (2008).
61 K. S. Yoo, V. V. Namboodiri, R. S. Varma, and P. G. Smirniotis, J. Catal., 222, 511 (2004).   DOI   ScienceOn
62 Z. C. Liu, Y. H. Zhang, C. P. Huang, J. S. Gao, and C. M. Xu, Chin. J. Catal., 25, 693 (2004).
63 C. P. Huang, Z. C. Liu, C. M. Xu, B. H. Chen, and Y. F. Liu, Appl. Catal., A, 277, 41 (2004).   DOI   ScienceOn
64 P. Wang, D. X. Wang, J. S. Gao, K. Dong, C. M. Xu, and J. J. Liu, Chem. J. Chin. Univ., 27, 1505 (2006).
65 A. S. Berenblyum, E. A. Katsman, and Y. Z. Karasev, Appl. Catal., A, 315, 128 (2006).   DOI
66 J. Zhang, C. Huang, B. Chen, P. Ren, and M. Pu, J. Catal., 249, 261 (2007).   DOI   ScienceOn
67 B. Sarup, S. I. Hommeltoft, M. Sylvest-Johansen, and P. Sugaard-Andersen, Proc. DGMK Conf. Catal. on Solid Acids and Bases, eds. J. Weitkamp and B. LuEcke, Berlin, Germany (1996).
68 S. Aschauer, L. Schilder, W. Korth, S. Fritschi, and A. Jess, Catal. Lett., 141, 1405 (2011).   DOI   ScienceOn
69 T. L. T Bui, W. Korth, S. Aschauerb, and A. Jess, Green Chem., 11, 1961 (2009).   DOI   ScienceOn
70 S. Tang, A. Scurto, and B. Subramaniam, J. Catal., 268, 243 (2009).   DOI   ScienceOn
71 Anonymous, Oil Gas J., 94, 69 (1996).
72 A. K. Rhodes, Oil Gas J., 92, 49 (1994).
73 P. Rao and S. R. Vatcha, Oil Gas J., 94, 56 (1996).