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Application of Chiral Ligands Heterogenized over Solid Supports on Enantioselective Catalysis  

Lee, Kwang-Yeon (Department of Chemical Engineering, Inha university)
Kawthekar, Rahul B. (Department of Chemical Engineering, Inha university)
Kim, Geon-Joong (Department of Chemical Engineering, Inha university)
Publication Information
Applied Chemistry for Engineering / v.17, no.6, 2006 , pp. 565-574 More about this Journal
Abstract
The trend towards the application of single enantiomers of chiral compounds is undoubtedly increasing. Among the various methods to obtain one single enantio-riched compound selectively, enantioselective catalysis is the most attractive method. Especially, it is important to increase the activity, selectivity and lifetime of usually expensive chiral catalysts with a minute quantity in the enantioselective synthesis. Immobilization of active homogeneous catalysts is a fashionable topic in asymmetric catalysis, providing the inherent advantage of easy separation and better handling properties. Many different ways have been investigated to improve the enantioselectivity of products and to recycle the catalysts. This review mainly focused on the present scope and limitations of different types of enantioselective heterogeneous catalysts.
Keywords
Immobilization; enantioselectivity; catalysis; chiral compound;
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