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http://dx.doi.org/10.9727/jmsk.2013.26.4.229

Characterization of Arsenic Sorption on Manganese Slag  

Seol, Jeong Woo (Department of Earth and Environmental Sciences and Research Institute of Natural Science (RINS), Gyeongsang National University)
Kim, Seong Hee (Department of Earth and Environmental Sciences and Research Institute of Natural Science (RINS), Gyeongsang National University)
Lee, Woo Chun (Department of Earth and Environmental Sciences and Research Institute of Natural Science (RINS), Gyeongsang National University)
Cho, Hyeon Goo (Department of Earth and Environmental Sciences and Research Institute of Natural Science (RINS), Gyeongsang National University)
Kim, Soon-Oh (Department of Earth and Environmental Sciences and Research Institute of Natural Science (RINS), Gyeongsang National University)
Publication Information
Journal of the Mineralogical Society of Korea / v.26, no.4, 2013 , pp. 229-244 More about this Journal
Abstract
Arsenic contamination may be brought about by a variety of natural and anthropogenic causes. Among diverse naturally-occurring chemical speciations of arsenic, trivalent (As(III), arsenite) and pentavalent (As(V), arsenate) forms have been reported to be the most predominant ones. It has been well known that the behavior of arsenic is chiefly affected by aluminum, iron, and manganese oxides. For this reason, this study was initiated to evaluate the applicability of manganese slag (Mn-slag) containing high level of Mn, Si, and Ca as an efficient sorbent of arsenic. The main properties of Mn-slag as a sorbent were investigated and the sorption of each arsenic species onto Mn-slag was characterized from the aspects of equilibrium as well as kinetics. The specific surface area and point of zero salt effect (PZSE) of Mn-slag were measured to be $4.04m^2/g$ and 7.73, respectively. The results of equilibrium experiments conducted at pH 4, 7 and 10 suggest that the sorbed amount of As(V) was relatively higher than that of As(III), indicating the higher affinity of As(V) onto Mn-slag. As a result of combined effect of pH-dependent chemical speciations of arsenic as well as charge characteristics of Mn-slag surface, the sorption maxima were observed at pH 4 for As(V) and pH 7 for As(III). The sorption of both arsenic species reached equilibrium within 3 h and fitting of the experimental results to various kinetic models shows that the pseudo-second-order and parabolic models are most appropriate to simulate the system of this study.
Keywords
manganese slag; trivalent arsenic (arsenite); pentavalent arsenic (arsenate); sorption;
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Times Cited By KSCI : 12  (Citation Analysis)
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