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Mineralogical Characterization of Buserite from the Janggun and Dongnam Mines, Korea  

Choi, Hun-Soo (Petroleum & Marine Resources Research Division, KIGAM)
Kim, Soo-Jin (School of Earth and Environmental Sciences, Seoul National University)
Kim, Jeong-Jin (Department of Earth and Environmental Sciences, Andong National University)
Publication Information
Journal of the Mineralogical Society of Korea / v.18, no.4, 2005 , pp. 259-266 More about this Journal
Abstract
X-ray diffraction (XRD), Electron microprobe analyses (EPMA) and heating experiments were used for mineralogical characterization of natural buserites collected from the Janggun and Dongnam mines. They are closely associated with $7-{\AA}$ phase (usually rancieite) in manganese oxide ores of the supergene oxidation zones of manganese carbonate deposits. Electron microprobe analyses give the average formula $(Ca_{0.78}Mg_{0.64}Mn^{2+}\;_{0.45})Mn^{4+}\;_{8.03}O_{18}\cdot13.2H_{2}O\;and\;(Zn_{0.81}Ca_{0.77}Mg_{0.26})Mn^{4+}\;_{8.00}O_{18}\cdot10.9H_{2}O$ for buserite from the Janggun and the Dongnam mine, respectively. The basal reflection of buserite from the Janggun mine shifts continuously from $9.86\;{\AA}\;at\;40^{\circ}C\;to\;7.60\;{\AA}\;at\;90^{\circ}C$, but the buserite from the Dongnam mine shows tendency of decreasing intensity in the $9.67^{\circ}C$ peak and of increasing intensity in the $7.53\;{\AA}$ peak in the range of $40\∼90^{\circ}C$, showing no gradual shifting of peaks.
Keywords
buserite; manganese oxide ore; Janggun mine; Dongnam mine; rancieite;
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