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On the Structure and the Extent of Disorder in Non-crystalline Silicates at High Pressure: 2 Dimensional Solid-state NMR Study  

Lee Sung Keun (School of Earth and Environmental Sciences, Seoul National University)
Publication Information
Journal of the Mineralogical Society of Korea / v.18, no.1, 2005 , pp. 45-52 More about this Journal
Abstract
The recent development and advances in 2 dimensional solid-state NMR, particularly, triple quantum (3Q) MAS NMR yield much improved resolution compared with conventional 1 dimensional MAS NMR, allowing us to study the distributions of cations and anions in the non-crystalline silicate glasses and melts. Here, we present the recent progress made by 3QMAS NMR spectra of silicate glasses quenched from melts at pressures up to 10 GPa in a multi-anvil apparatus, revealing previously unknown details of structures of covalent oxide glasses and melts at high pressure.
Keywords
silicate glasses and melts; 3QMAS NMR;
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