Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2020.30.3.117

Double-diffusive convection affected by conductive and insulating side walls during physical vapor transport of Hg2Br2  

Kim, Geug Tae (Department of Chemical Engineering, Hannam University)
Kwon, Moo Hyun (Department of Energy and Electrical Engineering, Woosuk University)
Abstract
In last few decades, although thermal and/or solutal buoyancy-driven recirculating flows in a closed ampoule have been intensively studies as a model problem, there exist interesting total molar flux of Hg2Br2 that have been unreported in the literature. It is concluded that the total molar flux of Hg2Br2(A) increases linearly and directly as the temperature difference regions in the range of 10℃ ≤ ΔT ≤ 50°, 3.5 × 103 ≤ Grt ≤ 4.08 × 103, 4.94 × 104 ≤ Grs ≤ 6.87 × 104. For the range of 10 Torr ≤ PB ≤ 150 Torr, the total molar flux of Hg2Br2(A) decays second order exponentially as the partial pressure of component B (argon as an impurity), PB increases. From the view point of energy transport, the fewer the partial pressure of component B (argon), PB is, the more the energy transport is achieved.
Keywords
Double diffusion; Physical vapor transport; $Hg_2Br_2$;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 M.I. Khana, F. Alzahrani, A. Hobiny and Z. Ali, "Modeling of Cattaneo-Christov double diffusions (CCDD) in Williamson nanomaterial slip flow subject to porous medium", J. Materials Res. Tech. (2020) in press.
2 I. Ahmad, M. Faisal and T. Javed, "Bi-directional stretched nanofluid flow with Cattaneo-Christov double diffusion", Results Phys. 15 (2019) 102581.   DOI
3 T. Muhammad, K. Rafique, M. Asma and M. Alghamdi, "Darcy-Forchheimer flow over an exponentially stretching curved surface with Cattaneo-Christov double diffusion", Physica A (2020) in press.
4 S.K. Asha and G. Sunitha, "Thermal radiation and Hall effects on peristaltic blood flow with double diffusion in the presence of nanoparticles", Case Studies in Thermal Engineering 17 (2020) 100560.   DOI
5 K.A. McCarthy, A.P. Goutzoulis, M. Gottlieb and N.B. Singh, "Optical rotatory power in crystals of the mercurous halides and tellurium dioxide", Opt. Commun. 64 (1987) 157.   DOI
6 R. Mazelsky and D.K. Fox, "Development of large single crystals for electronic, electro-optic and acoustooptic devices", Prog. Crystal Growth and Charact. 15 (1987) 75.   DOI
7 N.B. Singh, M. Gottlieb, A.P. Goutzoulis, R.H. Hopkins and R. Mazelsky, "Mercurous Bromide acoustooptic devices", J. Cryst. Growth 89 (1988) 527.   DOI
8 N.B. Singh, M. Marshall, M. Gottlieb, G.B. Brandt, R.H. Hopkins, R. Mazelsky, W.M.B. Duval and M.E. Glicksman, "Purification and characterization of mercurous halides", J. Cryst. Growth 106 (1990) 61.   DOI
9 N.B. Singh, M. Gottlieb and R. Mazelsky, "The optical quality of mercurous halides crystals", J. Cryst. Growth 128 (1993) 1053.   DOI
10 N.B. Singh, M. Gottlieb, R.H. Hopkins, R. Mazelsky, W.M.B. Duval and M.E. Glicksman "Physical vapor transport growth of mercurous chloride crystals", Prog. Crystal Growth and Charact. 27 (1993) 201.   DOI
11 N.B. Singh, M. Gottlieb, G.B. Branddt, A.M. Stewart, R.H. Hopkins, R. Mazelsky and M.E. Glicksman, "Growth and characterization of mercurous halide crystals: mercurous bromide system", J. Cryst. Growth 137 (1994) 155.   DOI
12 A.A. Kaplyanskii, V.V. Kulakov, Yu.F. Markov and C. Barta, "The soft mode properties in Raman spectra of improper ferroelastics $Hg_2Cl_2$ and $Hg_2Br_2$", Solid State Commun. 21 (1977) 1023.   DOI
13 M. Dalmon, S. Nakashima, S. Komatsubara and A. Mitsuishi, "Softening of acoustic and optical modes in ferroelstic phase in $Hg_2Br_2$", Solid State Commun. 28 (1978) 815.   DOI
14 J.S. Kim, S.B. Trivedi, J. Soos, N. Gupta and W. Palosz, "Growth of $Hg_2Cl_2$ and $Hg_2Br_2$ single crystals by physical vapor transport", J. Cryst. Growth 310 (2008) 2457.   DOI
15 T.H. Kim, H.T. Lee, Y.M. Kang, G.E. Jang, I.H. Kwon and B. Cho, "In-depth investigation of $Hg_2Br_2$ crystal growth and evolution", Materials 12 (2019) 4224.   DOI
16 P.M. Amarasinghe, J.S. Kim, H. Chen, S. Trivedi, S.B. Qadri, J. Soos, M. Diestler, D. Zhang, N. Gupta and J.L. Jensen, "Growth of high quality mercurous halide sing crystals by physical vapor transport method for AOM and radiation detection applications", J. Cryst. Growth 450 (2016) 96.   DOI
17 G.T. Kim and M. H. Kwon, "Effects of solutally dominant convection on physical vapor transport for a mixture of $Hg_2Br_2$ and $Br_2$ under microgravity environments", Korean Chem. Eng. Res. 52 (2014) 75.   DOI
18 G.T. Kim and M.H. Kwon, "Numerical analysis of the influences of impurity on diffusive-convection flow fields by physical vapor transport under terrestrial and microgravity conditions: with application to mercurous chloride", Appl. Chem. Eng. 27 (2016) 335.   DOI
19 S.H. Ha and G.T. Kim, "Preliminary studies on doublediffusive natural convection during physical vapor transport crystal growth of $Hg_2Br_2$ for the spaceflight experiments", Korean Chem. Eng. Res. 57 (2019) 289.   DOI
20 W.M.B. Duval, "Transition to chaos in the physical transport process-I", the Proceeding of the ASME-- WAM Winter Annual meeting, Fluid mechanics phenomena in microgravity, ASME-WAM, Nov. 28 -- Dec. 3, New Orleans, Louisiana (1993).
21 S.V. Patankar, "Numerical Heat Transfer and Fluid Flow" (Hemisphere Publishing Corp. Washington D.C. 1980) p. 131.