Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2020.30.2.066

Comparison of plasma resistance between spray coating films and bulk of CaO-Al2O3-SiO2 glasses under CF4/O2/Ar plasma etching  

Na, Hyein (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology)
Park, Jewon (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology)
Park, Jae-Hyuk (IONES. Co. Ltd.)
Kim, Dae-Gun (IONES. Co. Ltd.)
Choi, Sung-Churl (Division of Materials Science and Engineering Hanyang University)
Kim, Hyeong-Jun (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology)
Abstract
The difference of plasma resistance between the CAS glass bulk and coating films were compared. Plasma resistance was confirmed by analyzing the etch rate and the microstructure of the surface when the CAS glass bulk and the glass coating film were etched with CF4/O2/Ar plasma gas. CAS glass coating film was etched up to 25 times faster than the glass bulk. A statistically high correlation between the surface roughness and the etching rate of the coating film was derived, and thus, the high surface roughness of the coating film was determined to cause rapid etching. In addition, cristobalite crystals that has a low Ca content and a high Si content, was foamed on the glass coating film. Therefore, the CAS glass coating film is considered to have low plasma resistance compared to the glass bulk.
Keywords
Corrosion; Sintering; $CaO-Al_2O_3-SiO_2$ (CAS) glass; Surface roughness;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 T. Nam, H. Lee, T. Choi, S. Seo, C.M. Yoon, Y. Choi, H. Jeong, H.K. Lingam, V.R. Chitturi, A. Korolev, J.H. Ahn and H. Kim, "Low-temperature, high-growth-rate ALD of $SiO_2$ using aminodisilane precursor", Appl. Surf. Sci. 485 (2019) 381.   DOI
2 R. Pierron, S. Lecler, J. Zelgowski, P. Pfeiffer and F. Mermet, "Etching of semiconductors and metals by the Photonic Jet with shaped optical fiber tips", Appl. Surf. Sci. 418 (2017) 452.   DOI
3 K.C. Yang, Y.J. Shin, H.W. Tak, W. Lee, S.B. Lee and G.Y. Yeom, "Effects of superimposed dual-frequency (13.56/2 MHz) inductively coupled plasma source on the uniformity of $Ar/CF_4$ plasma", Vacuum 168 (2019) 108802.   DOI
4 S.J. Park, J.K. Lee, Y.S. Oh, S. Kim, H. Kim and S. Lee, "The effects of water addition on the color and crystalline phase of $Y_2O_3$ coatings fabricated by plasma suspension spray", J. Korean Ceram. Soc. 53 (2016) 641.   DOI
5 J.K. Lee, S.J. Park, S. Kim, H. Kim and S.M. Lee, "Fragmentation behavior of $Y_2O_3$ suspension in axially fed suspension plasma spray", Surf. Coat. Technol. 309 (2017) 456.   DOI
6 J.H. Choi, H. Na, J. Park and H.J. Kim, "Plasma corrosion resistance of aluminosilicate glasses containing Ca, Y and B under fluorocarbon plasma with $Ar^+$", J. Non-Cryst. Solids 521 (2019) 119498.   DOI
7 J.H. Choi, H.B. Park, H. Na and H.J. Kim, "Plasma corrosion resistance of $RO-Al_2O_3-SiO_2$ (R: Alkaline Earth) under fluorocarbon plasma with $Ar^+$: II. Plasma resistant glass", Corros. Sci. 146 (2019) 247.   DOI
8 H. Na, J. Park, S.C. Choi and H.J. Kim, "The Effect of composition of Plasma Resistance of $CaO-Al_2O_3-SiO_2$ glasses under Fluorocarbon Plasma with $Ar^+$", Appl. Surf. Sci. 476 (2019) 663.   DOI
9 H. Na, J. Park, S.C. Choi and H.J. Kim, "A study of sintering behavior of spray coating in $CaO-Al_2O_3-SiO_2$ glasses on $Al_2O_3$ substrate", J. Korean Cryst. Growth Cryst. Technol. 29 (2019) 298.   DOI
10 S. Satsuka, T. Sakaino and K. Takahashi, "Glass handbook", ed. 3 (Asakura Shoten, Tokyo, 1975) p. 888.
11 Y. Masayuki, "For the first time to make glass", Ceramics Basic Lecture/Tokyo Institute of Technology School of Engineering, Department of Inorganic Materials Engineering, ed. 4 (Uchida Old Crane Field, Tokyo, 1991).
12 G.H. Hwang, H.J. Jeon and Y.S. Kim, "Physical properties of barrier ribs of plasma display panels: 1, Formation of pores during sintering of lead borosilicate glass frits", J. Am. Ceram. Soc. 85 (2002) 2956.   DOI
13 K.H. Jun, "Study on the bloating mechanism for artificial lightweight aggregate of surface reforming", Department of Material Science & Engineering Graduate School Kyonggi University (2012).
14 E.M. Rabinovich, "Preparation of glass by sintering", J. Mate. Sci. 20 (1985) 4259.   DOI
15 A. Karamanov and M. Pelino, "Sinter-crystallisation in the diopside-albite system Part I. Formation of induced crystallisation porosity", J. Eu. Ceram. Soc. 26 (2006) 2511.   DOI
16 E.D. Zanotto and A. Galhardi, "Experimental test of the general theory of transformation kinetics: Homogeneous nucleation in a $Na_2O-2CaO-3SiO_2$ glass", J. Non-Cryst. Solids 104 (1988) 73.   DOI
17 M.O. Prado and E.D. Zanotto, "Glass sintering with concurrent crystallization", C. R. Chimie 5 (2002) 773.   DOI
18 J.B. Parise, A.Y. Haeri, D.J. Weidner, J.D. Jorgensen and M.A. Saltzberg, "Pressure-induced phase transition and pressure dependence of crystal structure in low (${\alpha}$) and Ca/Al-doped cristobalite", J. Appl. Phys. 75 (1994) 1361.   DOI
19 F. Pei, "Influence of low magnesia content on the $CaO-Al_2O_3-SiO_2$ glass-ceramics: Its crystallization behavior, microstructure and physical properties", Ceram. Inter. 44 (2018) 20132.   DOI
20 S.H. Abd E Rahim, A.A. Melegy and E.M.A. Hamzawy, "Wollastonite-pseudoollastonite from silica fume, limestone and glass cullet composite", Inter Ceram (2017) 232.