Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2018.28.6.229

The properties of glass ceramics of Li2O-Al2O3-SiO2 system according to nucleation agent  

Park, Hyun-Wook (Korea Institute of Ceramic Engineering and Technology, Optic & Display Material Center)
Lee, Ji-Sun (Korea Institute of Ceramic Engineering and Technology, Optic & Display Material Center)
Lim, Tae-Young (Korea Institute of Ceramic Engineering and Technology, Optic & Display Material Center)
Hwang, Jonghee (Korea Institute of Ceramic Engineering and Technology, Optic & Display Material Center)
Ra, Yong-Ho (Korea Institute of Ceramic Engineering and Technology, Optic & Display Material Center)
Noh, Myoung-Rae (Samkwang Glass CO. LTD.)
Seo, Kwan-Hee (Samkwang Glass CO. LTD.)
Kim, Jin-Ho (Korea Institute of Ceramic Engineering and Technology, Optic & Display Material Center)
Abstract
The glass-ceramic of $Li_2O-Al_2O_3-SiO_2$ system was synthesized by using $ZrO_2$, $ZrSiO_4$, $ZrOCl_2$ and $Zr(SO_4)_2$, which is a raw material of Zr serving as a nucleation agent. It was confirmed that Avrami parameter of these four glasses is over 3 for bulk crystallization. The glass synthesized by $ZrOCl_2$, and $Zr(SO_4)_2$ showed high melting quality during the melting process. It is also observed that the Zr component is uniformly distributed in the glass. Various characterizations was evaluated, including composition analysis and bending strength.
Keywords
Glass-Ceramic; Crystallization; Nucleation agent; Avrami parameter; DTA;
Citations & Related Records
연도 인용수 순위
  • Reference
1 R. Roy, D.M. Roy and E.F. Osborn, "Compositional and stability relationships among the lithium aluminosilicates: Eucryptite, spodumene and petalite", J. Am. Ceram. Soc. 33 (1950) 152.   DOI
2 H. Dislish and P. Hinz, "History and principles of the sol-gel process, and some new multicomponent oxide coationgs", J. Non-Crystal. Solids 48 (1982) 11.   DOI
3 M. Guedes, A.C. Ferro and J.M.F. Ferreira, "Nucleation and crystal growth in commercial LAS compositions", J. Euro. Ceram. Soc. 21 (2001) 1187.   DOI
4 P.F. James, "Nucleation in glass-forming systems a review", Edited by J.H. Simmons, D.R. Uhlmann and G.H. Beall, Vol. 4 (Columbus, Ohio, 1982) p. 1.
5 D.R. Uhlmann, "Crystal growth in glass-forming systems: A ten-year perspective", Edited by J.H. Simmons, D.R. Uhlmann and G.H. Beall, American Ceramic Society, Vol. 4 (Columbus, Ohio, 1982) p. 80.
6 S.W. Lee, K.B. Shim and K.H. Auh "Application of crystallization kinetics on differential thermal analysis", J. Kor. Ceram. Soc. 35 (1998) 1162.
7 C.S. Ray and D.E. Day, "Ceramic transactions nucleation and crystallization in liquid and glasses", M.C. Weinberg, Vol. 30 (The American Ceramic Society, Ohio, 1993) p. 207.
8 S.W. Lee, B. Deshpande, R. Stevens and P. Knott, "Determination of the nucleation rate curve for lead titanate glass by differential thermal analysis", Phys. Chem. Glasses 37 (1996) 223.
9 H.E. Kissinger, "Reaction kinetics in differential thermal analysis", Analytical Chem. 29 (1957) 1702.   DOI
10 Y.W. Park and Y.W. Kim, "A study on the transparent glass-ceramics on $Al_2O_3$-$SiO_2$ system", J. Kor. Ceram. Soc. 29 (1992) 223.
11 H.J. Borchardt, "Initial reaction rates form DTA", J. Inorg. Nucl. Chem. 12 (1960) 252.   DOI
12 K. Matusita, S. Sakka and Y. Matsui, "Determination of the activation energy for crystal gtowth by differential thermal anaysis", J. Mat. Sci. 10 (1975) 961.   DOI
13 M. Avrami, "Kinetics of phase change", J. Chem. Phys. 7 (1939) 1103.   DOI
14 W.A. Johnson and K.F. Mehl, "Reaction kinetics in process of nucleation and growth", Trans. AIME 135 (1939) 416.
15 H.E. Kissinger, "Variation of peak temperature with heation rate differential thermal analysis", J. Res. Natl. Bureau Stand. 57 (1956) 217.   DOI
16 J.A. Augis and J.E. Bennett, "Calculation of the avrami parameters for heterogeneous solid state reactions using a modification of the kissinger method", J. Therm. Anal. 13 (1978) 283.   DOI
17 L. Barbieri, A.B. Corradi, C. Leonelli, C. Siligardi, T. Manfredini and G.C. Pellacani, "Effect of $TiO_2$ addition on the properties of complex aluminosilicate glasses and glass-ceramics", Mater. Res. Bull. 32 (1997) 637.   DOI
18 M. Ashizuka and E. Ishida, "Mechanical properties of silicate glass-ceramics containing tricalcium phosphate" J. Master. Sci. 32 (1997) 185.   DOI
19 J. Ma. Rincon, M. Romero, J. Marco and V. Caballer, "Some aspects of crystallization microstructure on new glass-ceramic glazes", Mater. Res Bull. 33 (1998) 1159.   DOI
20 M. Romero, J. Ma. Rincon and A. Acosta, "Effect of iron oxide content on the crystallisation of a diopside glass-ceramic glasze", J. Eur. Ceram. Soc. 22 (2002) 883.   DOI
21 T. Owawa, "Kinetics of non-isothermal crystallization", Polymer. 12 (1971) 150.   DOI
22 W. Sack and H. Scheidler, "Effects of the nucleating agents $TiO_2$ and $ZrO_2$ on crystal phases formed during development of glass-ceramics", Glastech. Ber. 126 (1966) 39.