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http://dx.doi.org/10.6111/JKCGCT.2018.28.1.028

Fabrication and characteristics of NTC thermistor for low temperature sintering  

Koo, Bon Keup (Department of Materials Science and Engineering, Hanbat National University)
Abstract
In order to study the NTC thermistor that can be fired at low temperature, the influence of the lead free glass frit and $RuO_2$ addition on the electrical properties of the NTC thermistor of $Mn_{1.85}Ni_{0.25}Co_{0.9}O_4$ basic composition was studied. The sintering characteristics of the specimen sintered at $1000^{\circ}C$ with 10 wt% frit added to the basic NTC composition were similar to those of the specimen sintered at $1200^{\circ}C$ without frit. However, as the amount of frit increased, the electrical resistivity and B constant were increased. In order to reduce the resistance, NTC thermistor was prepared by adding 0, 2, and 5 wt% of $RuO_2$ to the composition containing 10 wt% of frit and sintered at $1000{\sim}1200^{\circ}C$, and sintering and electrical properties were measured. The electrical resistivity and the B constant tended to decrease with increasing $RuO_2$ content. However, the resistivity was the lowest at sintering temperature of $1000^{\circ}C$ and the resistance increased with increasing sintering temperature after 5 wt% $RuO_2$ addition. The NTC thermistor sintered at $1000^{\circ}C$ with 10 wt% frit and 5 wt% $RuO_2$ in the composition of NTC showed similar electrical properties and sintering characteristics when sintered at $1200^{\circ}C$ without added frit.
Keywords
NTC thermistor; Low temperature sintering; Lead free frit; Ruthenium oxide;
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1 F. Al-Turjman, A. Radwan, S. Mumtaz and J. Rodriguez, "Mobile traffic modelling for wireless multimedia sensor networks in IoT", Computer Comm. 112 (2017) 109.
2 J. Yuan, J. Zhang, S. Ding and X. Dong, "Cooperative localization for disconnected sensor networks and a mobile robot in friendly environments", Information Fusion 37 (2017) 22.
3 T.G. Nenov and S.P. Yordanov, "Ceramic sensors : Technology and applications", CRC Press (1996) p. 1.
4 H. Takuoki, K. Takayuki and M. Yoshihiro, "New thermistor materials", National Technical Report (1982) p. 1123.
5 T.G. Nenov and S.P. Yordanov, "Ceramic sensors : Technology and applications", CRC Press (1996) p. 296.
6 S. Jagtap, S. Rane, S. Gosavi and D. Amalnerkar, "Study of microstructure, impedance and dc electrical properties of $RuO_2$-spinel based screen printed 'green' NTC thermistor", Curr. Appl. Phys. 10 (2010) 1156.
7 E. Elbadraoui, J.I. Baudour, B. Gillot, S. Fritsch and A. Rousset, "Cation distribution and mechanism of electrical conduction in Nikel-copper manganite spinels", Solid State Ion. 93 (1997) 219.
8 J.I. Leem T.W. Kim, J.Y. Shin and J.H. Ryu, "Preparation and characterization of Mn-Co-Ni NTC thermistor", J. Korean Cryst. Growth Cryst. Technol. 25 (2015) 80.
9 S. Jagtap, S. Rane, S. Gosavi and D. Amalnerkar, "Preparation, characterization and electrical properties of spinel-type environment frindly thick film NTC thermistors", J. Eur. Ceram. Soc. 28 (2008) 2501.
10 S. Jagtap, S. Rane and S. Gosavi, "Synthesis, characterization and fabrication of NTC thick film thermistor using lead free glass frit", J. Mater. Sci. Eng. A 6 (2016) 301.
11 M. Hrovat, D. Belavic, J. Kita, J. Hole, J. Cilensek and S. Drnovsek, "Thick film NTC thermistor and LTCC materials: The dependence of the electrical and microstructure characteristics on the firing temperature", J. Eur. Ceram. Soc. 29 (2009) 3265.
12 B.K. Koo, "Effect of lead free glass frit compositions on properties of Ag system conductor and $RuO_2$ based resistor pastes" J. Korean Electr. Electron. Mater. Eng. 24 (2011) 200.
13 W. Vogel, "Chemistry of Glass", Am. Ceram. Soc. Inc. Columbus, (1979) p. 298.
14 K. Bobran, A. Kusy, A. Witold and G. Wilczynski, "Conduction in $RuO_2$-based thick film", International J. Electronics 78 (1996) 113.
15 M.N. Muralidharan, P.R. Rohini, E.K. Sunny, K.R. Dayas and A. Seema, "Effect of Cu and Fe addition on electrical properties of Ni-Mn-Co-O NTC thermistor composition", Ceramics International 38 (2012) 6481.
16 P.J. Holmes and R.G. Loasby, "Handbook of thick film technology" (Electrochemical Pub. Limited 1976) p. 97.
17 R.W. Vest, "Materials science and thick film technology", J. Am. Ceram. Bull. 65 (1986) 631.
18 B.K. Koo and H.G. Kim, "Microstructure and electrical properties of $RuO_2$ system thick film resistors", J. Kor. Ceram. Soc. 27 (1990) 337.
19 B.K. Koo, "Effect of lead free glass frit compositions on properties of Ag system conductor and $RuO_2$ based resistor paste", J. Korean Electr. Electron. Mater. Eng. 24 (2011) 200.
20 W.D. Ryden and A.W. Lawson, "Temperature dependence of the resitivity of $RuO_2$ and $IrO_2$", Phys. Letters 26A (1968) 209.
21 R.G. Johnston, "Oxides containing ruthenium in nuclear waste disposal", Ph.D. Thesis, Pennsylvania State University (1980).
22 F. Garisto, "Thermodynamic behaviour of ruthenium at high temperatures" (Atomic Energy of Canada Ltd., Pinawa, 1988) p. 4.