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http://dx.doi.org/10.6111/JKCGCT.2017.27.5.249

The study of geopolymer utilization of reclaimed ash by using magnetic separation method  

Kim, Kangduk (Department of Advanced Materials Engineering, Kyonggi University)
Abstract
Using a magnetic separation process, pond ash generated in thermoelectric power plants was separated into magnetic materials and nonmagnetic materials in order to make it into a raw material of geopolymers and unburned carbon; screening characteristics according to the particle sizes and magnet strength levels of the pond ash were observed. Based on the results of magnetic separation into fine particle (0.15~0.84 mm) and rough particle (0.84~2.4 mm) pond ash using 3000 G magnets, the weight fraction and ignition loss of nonmagnetic materials were found to be higher than those of magnetic materials, regardless of the particle size. In the case of fine particle pond ash, when the magnet strength was increased from 3000 G to 10000 G, even those materials that were weakly magnetic were separated into magnetic materials, leading to drastic increases in the weight fraction of magnetic materials, such that the ignition loss accounted for 66.9 % (22.8 wt%) of the entire ignition loss of 32.6 wt%, despite of the low ignition loss. Based on the results of measurement of the compressive strength levels of geopolymers made of magnetic-separated rough particle pond ash, the compressive strength of geopolymers made of magnetic materials containing small amounts of unburned carbon was found to be 20 MPa.
Keywords
Reclaimed ash; Magnetic separation; Unburned carbon; Geopolymer;
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Times Cited By KSCI : 5  (Citation Analysis)
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1 S.J. Lee, S.Y. Im, J.W. Jeong, J.Y. Kong and B.S. Chun, "An analysis on thermal characteristic of controlled low strength materials with coal ash for pipe-backfill", 2012 Korean Geo-Environmental Society Conference (2012) 149.
2 J.Y. Kong, H.S. Jung, B.J. Huh and B.S. Chun, "Fresh properties and environmental assessment of controlled low strength materials made with coal ash", Geo-environmental and Slope Conference (2010) 83.
3 K.D. Kim, J.H. Kim, Y.T. Kim, S.G. Kang and K.G. Lee, "Production of lightweight aggregates using power plant reclaimed ash", J. of the Kor. Ceramic Soc. 47 (2010) 583.   DOI
4 H.G. Hyun, H.G. Kim and B.S. Chun, "Characteristics of the freezing and thawing for controlled low-strength material using pond ash", J. of the Geo-environmental Society 11 (2010) 51.
5 K.K. Kuk, H.Y. Kim and B.S. Chun, "A study on the engineering characteristics of power plant coal ash", J. of the Geo-environmental Society 11 (2010) 25.
6 B.C. Han, H.D. Yun and S.Y. Chung, "Flexural behavior of reinforced high-strength lightweight concrete beams with bottom ash aggregates", Journal of the architectural institute of Korea (Structure & Construction) 17 (2001) 37.
7 B.S. Chun and Y.H. Yeoh, "A study on the recycling of coal ash as structural backfill materials", J. Kor. Soc. Ocean Eng. 14 (2000) 74.
8 W.G. Shin, D.S. Lim and B.S. Chun, "A study on selfhardening characteristic of coal ash by mixing ratio of fly ash and bottom ash", J. of the Geo-environmental Society 11 (2010) 85.
9 K.P. Lee, Y.S. Do, S.S. Lee and H.Y. Song, "A study on optimum mixing derivation of the environment-friendly high performance geopolymer paste", Jounal of Proceeding the Korea Institute of Building Construction 9 (2009) 107.
10 J.T. Kim, D.S. Seo, G.J. Kim and J.K. Lee, "Influence of alkaline-activator content on the compressive strength of aluminosilicate-based geoploymer", J. of the Kor. Ceramic Soc. 47 (2010) 216.   DOI
11 R. Thakur and S. Ghosh, "Hight temperature resistant fly ash based geopolymer composite", LAP LAMBERT Academic Publishing (2011).
12 R. Thakur and S. Ghosh, "Fly ash based geopolymer composites", LAP LAMBERT Academic Publishing (2011).
13 J. Davidovits, "Geopolymer chemistry and applications", Institut Geopolymere (2008).
14 J.L. Provis and J.S.J. van Deventer (Ed.), "Geopolymers", Woodhead Publishing Limited (2009).
15 S.J. Lee, M.D. Seo, Y.J. Kim, H.H. Park, T.N. Kim, Y. Hwang and S.B. Cho, "Unburned carbon removal effect on compressive strength development in a honeycomb briquette ash-based geopolymer", International J. of Mineral Processing 97 (2010) 20.   DOI
16 J.C. Hower, R.F. Rathbone, J.D. Robertson, G. Peterson and A.S. Trimble, "Petrology, mineralogy, and chemistry of magnetically-separated sized fly ash", Fuel 78 (1999) 197.   DOI
17 T.H. Ha, S. Muralidharan, J.H. Bae, Y.C. Ha, H.G. Lee, K.W. Park and D.K. Kim, "Effect of unburned carbon on the corrosion performance of fly ash cement mortar", Construction and Building Materials 19 (2005) 509.   DOI
18 P. Sultana, S. Das, A. Bhattacharya, R. Basu and P. Nandy, "Mullite formation in coal fly ash is facilitated by the incorporation of magnesium oxide", Rev. Adv. Mater. Sci. 27 (2011) 69.
19 A.S. Shoumkova, "Magnetic separation of coal fly ash from Bulgarian power plant", Wast Management Res. 29 (2011) 1078.   DOI
20 N.L. Um, G.C. Han, K.S. You, H.C. Cho and J.W. Ahn, "Separation of ferrous materials from municipal solid waste incineratiion bottom ash", J. of Korean Ins. of Resources Recycling 16 (2007) 19.
21 Korea Concrete Institute, "Advanced concrete engineering for special uses", Kimundang, Korea (2004) 252.
22 N.H. Kang, C.M. Chon, H.T. Jou and S.J. Lee, "Effect of particle size and unburend carbon content of fly ash from hadong power plant on compressive strength of geopolymers", Kor. J. Mater. Res. 23 (2013) 510.   DOI