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http://dx.doi.org/10.6111/JKCGCT.2015.25.5.225

Crystal structure of Mn-Co-Ni thermistor  

Lee, Jung-Il (Department of Materials Science and Engineering, Korea National University of Transportation)
Mhin, Sungwook (Heat Treatment R&D Group, Korea Institute of Industrial Technology)
Ryu, Jeong Ho (Department of Materials Science and Engineering, Korea National University of Transportation)
Abstract
This study was performed to investigate crystal structure of cubic spinel-type monophase oxide composed of the Mn-Co-Ni ternary system. Starting material was prepared by mixing Mn, Co, Ni oxides then evaporation to dryness. The XRD patterns were analyzed by in-situ XRD as increasing temperature from room temperature to $1400^{\circ}C$ in air atmosphere. The cubic spinel phase was existed in a temperature range from $900^{\circ}C$. However, separation of NiO phase was detected from $1300^{\circ}C$, which was the origin of deterioration in the crytallinity. The surface morphology of the manufactured NTC thermistors were analyzed by FE-SEM for comparison of good and bad samples.
Keywords
NTC thermistor; Crystal structure; In-situ XRD;
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