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http://dx.doi.org/10.6111/JKCGCT.2015.25.2.045

Characterizations of graded AlGaN epilayer grown by HVPE  

Lee, Chanbin (Department of Electronic Material Engineering, Korea Maritime and Ocean University)
Jeon, Hunsoo (Department of Electronic Material Engineering, Korea Maritime and Ocean University)
Lee, Chanmi (Department of Electronic Material Engineering, Korea Maritime and Ocean University)
Jeon, Injun (Department of Electronic Material Engineering, Korea Maritime and Ocean University)
Yang, Min (Department of Electronic Material Engineering, Korea Maritime and Ocean University)
Yi, Sam Nyung (Department of Electronic Material Engineering, Korea Maritime and Ocean University)
Ahn, Hyung Soo (Department of Electronic Material Engineering, Korea Maritime and Ocean University)
Kim, Suck-Whan (Department of Physics, Andong National University)
Yu, Young Moon (LED-MCT R&BD Center, Pukyong National University)
Sawaki, Nobuhiko (Department of Electrical and Electronics Engineering, AIT)
Abstract
Compositionally graded AlGaN epilayer was grown by HVPE (hydride vapor phase epitaxy) on (0001) c-plane sapphire substrate. During the growth of graded AlGaN epilayer, the temperatures of source and the growth zone were set at $950^{\circ}C$ and $1145^{\circ}C$, respectively. The growth rate of graded AlGaN epilayer was about 100 nm/hour. The changing of Al contentes was investigated by field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS). From the result of atomic force microscope (AFM), the average of roughness in 2 inch substrate of graded AlGaN epilayer was a few nanometers scale. X-ray diffraction (XRD) with the result that the AlGaN (002) peak ($Al_{0.74}Ga_{0.26}N$) and AlN (002) peak were appeared. It seems that the graded AlGaN epilayer was successfully grown by the HVPE method. From these results, we expect to use of the graded AlGaN epilayer grown by HVPE for the application of electron and optical devices.
Keywords
Graded AlGaN epilayer; FE-SEM; AFM; XRD; HVPE;
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1 S. Nakamura and G. Fasol, "The blue laser diode", (Springer, Berlin, 1997) 3.
2 Y.J. Yu, M.Y. Ryu, P.W. Yu, D.J. Kim and S.J. Park, "Optical investigation of InGaN/GaN quantum well structures with various barrier widths", J. Korean Phys. Soc. 28 (2001) 134.
3 J.H. Chen, Z.C. Feng, H.L. Tsai, J.R. Yang, P. Li, C. Wetzel, T. Detchprohm and J. Nelson, "Optical and structural properties of InGaN/GaN multiple quantum well structrure grown by metalorganic chemical vapor deposition", Thin Solid Films 498 (2005) 123.
4 H.M. Kim, J.S. Choi, J.E. Oh and T.K. Yoo, "Cathodoluminescence characterization of GaN thick films grown by using the HVPE method", J. Korean Phys. Soc. 37 (2000) 956.   DOI   ScienceOn
5 S.L. Hwang, K.H. Kim, H.S. Jeon, C.H. Lee, S.H. Hong, I.H. Heo, M. Yang, H.S. Ahn, S.W. Kim, S.C. Lee, I.S. Cho, W.T. Lim, J.H. Lee and S.K. Shee, "Characterization of a SAG-InGaN/AlGaN LED by mixed-source HVPE with a multi-sliding boat system", J. SID 16, 4 (2008) 541.
6 M. Kim, M.J. Shin, H.S. Jeon, H.S. Ahn, S.N. Yi, S.C. Choi, S.G. Lee, Y.M. Yu and N. Sawaki, "Crystal orientation of GaN nanostructures grown on $Al_2O_3$ and Si(111) with a Zr buffer layer", Jpn. J. Appl. Phys. 51 (2012) 1.
7 Z.C. Feng, "III-Nitride semiconductor materials" (World Scientific, Singapore, 2006) 1.
8 Z.C. Feng, "III-Nitride semiconductor materials" (World Scientific Singapore, 2006) 17.
9 I.S. Seo and S.J. Lee "The role of AlN buffer layer in $Al_xGa_{1-x}N/GaN$ heterostructures with x from 0.35 to 0.5 grown on sapphire (0 0 0 1)", J. Cryst. Growth 241 (2002) 297.   DOI   ScienceOn
10 D. Tsvetkov, Y. Melnik, A. Davydov, A. Shapiro, O. Kovalenkov, J. B Lam, J.J. Song and V. Dmitriev, "Growth of submicron AlGaN/GaN/AlGaN heterostructures by hydride vapor phase epitaxy (HVPE)", Phys. Stat. Solidi (c) 188, 1 (2001) 429.   DOI
11 S. Nakamura, M. Senoh, S. Nagahama, N. Iwasa, T. Yamada, T. matsushita, Y. Sugimoto and H. Kiyoku, "InGaN-based multi-quantum-well-structure laser diodes", J. Appl. Phys. Lett. 70 (1997) 14.
12 S. Rajan, S.P. DenBaars, U.K. Mishra, H. Xing and D. Jena, "Electron mobility in graded AlGaN alloys", J. Appl. Phys. Lett. 88 (2006) 1.
13 E.C. Yong, F. Wu, A.E. Romanov, D.A. Haeger, S. Nakamura, S.P. Denbaars, D.A. Cohen and J.S. Speck, "Compositionally graded relaxed AlGaN buffers on semipolar GaN for mid-ultraviolet emission", J. Appl. Phys. Lett. 101 (2012) 9.
14 P. Das, N. Halder, R. Kumar, S.K. Jana, S. Kabi, B. Borisov, A. Dabiran, P. Chow and D. Biswas, "Graded barrier AlGaN/AlN/GaN heterostructure for improvved 2DEG carrier concentration and mobility", Electron Mater. Lett. 10, 6 (2014) 1087.   DOI   ScienceOn
15 A. Able, W. Wegscheider, K. Engl and J. Zweck, "Growth of crack-free GaN on Si (111) with graded AlGaN buffer layers", J. Cryst. Growth 276, 3 (2005) 415.   DOI   ScienceOn
16 D. Guojian, G. Liwei, X. Zhigang, C. Yao, X. Peiqiang, J. Haiqiang, Z. Junming and C. Hong, "Characteristics of GaN grown on 6H-SiC with different AlN buffers", J. Cond. 31, 3 (2010) 3.
17 S.G. Jung, H.S. Jeon, G.S. Lee, S.M. Bae, W.I. Yun, K.H. Kim, S.N. Yi, M. Yang, H.S. Ahn, S.W. Kim, Y.M. Yu, S.H. Cheon and H.J. Ha, "The properties of AlGaN epi layer grown by HVPE", J. Korean Cryst. Growth Cryst. Technol. 22 (2012) 11.
18 L.W. Kumar, V. Piner, E.L. Adesida and L. Ilesanmi, "DC, RF, and microwave noise performance of AlGaNGaN field effect transistors dependence of aluminum concentration", IEEE Trans. On Electron Devices. 50, 4 (2003) 1069.   DOI   ScienceOn
19 S. Oktyabrsky, Y. Nishi, S. Koveshnikov, W.E. Wang, N. Goel and W. Tsai, "Materials and technologies for III-V MOSFETs", Fundamentals of III-V Semiconductor MOSFETs (2010) 195.
20 Y.L Hsiao, Y.J. Wang, C. Chang, Y.C. Weng, Y.Y. Chen, K.W. Chen, J.S. Maa and E.Y. Chang, "Investigation of the low-temperature AlGaN interlayer in AlGaN/GaN/ AlGaN double heterostructure on Si substrate", Appl. Phys. Lett. 7, 11 (2014) 1.
21 K.H. Kim, K.S. Jang, S.L. Hwang, H.S. Jeon, W.J. Choi, M. Yang, H.S. Ahn, S.W. Kim, Y. Honda, M. Yamaguchi, N. Sawaki, J. Yoo, S.M. Lee and M. Koike, "Fabrication of SAG-AlGaN/InGaN/AlGaN LEDs by mixed-source HVPE with multi-sliding boat system", Phys. Stat. Solidi (c) 4 (2007) 29.   DOI   ScienceOn