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http://dx.doi.org/10.6111/JKCGCT.2012.22.5.227

Thermal stability of surface modified Ni-Cr-alloys in molten FLiNaK salt  

Kwang, Hyun Cho (Department of Nanomechatronics Engineering, Pusan National University)
Bang, Hyun (Division of Mechanical and Energy Systems Engineering, Korea Maritime University)
Lee, Tae Suk (Department of Materials Engineering, Korea Maritime University)
Lee, Byeong Woo (Department of Materials Engineering, Korea Maritime University)
Abstract
Inconel 617 and Hastelloy X are the most promising candidate materials for the heat exchanger of next generation nuclear reactor. Surface coating and its effects on high temperature properties for the Inconel 617 and Hastelloy X under molten FLiNaK (LiF-NaF-KF) salt environment have been investigated. For TiAlN and $Al_2O_3$ overlay coatings, the two different PVD (physical vapor deposition) methods of an arc discharge and a sputtering were applied, respectively. A study for the thermal stability of the surface modified Ni-Cr alloy substrates has been conducted. To evaluate the corrosion mechanism of Ni-Cr alloys in the molten salt, a ruptured Inconel pipe used for the molten salt transportation has been analyzed. The thermal properties of morphological and structural properties each sample were characterized before and after heat-treatment at $600^{\circ}C$ in molten FLiNaK salt. The results showed that the TiAlN and $Al_2O_3$ overlay coated specimens had the enhanced high temperature stability.
Keywords
Inconel 617; Hastelloy X; FLiNaK salt; Coating; Thermal stability;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 Next generation nuclear plant materials research and development program plan, INL/EXT-06-11701, Rev. 4 (2007).
2 D.F. Williams, Assessment of candidate molten salt coolants for the NGNP/NHI heat-transfer loop, ORNL/TM-2006/69 (2006).
3 D.F. Williams, L.M. Toth and K.T. Clarno, "Assessment of candidate molten salt coolants for the advanced high-temperature reactor (AHTR)", ORNL/TM-2006/12 (2006).
4 M. Shindo and H. Nakajima, "Evaluation of $Al_{2}O_{3}$ and TiN coating on Hastelloy XR alloy under aggressive conditions", ISIJ Int. 29 (1989) 793.   DOI
5 K.A. Gruss and R.F. Davis, "Adhesion measurement of zirconium nitride and amorphous silicon carbide coatings to nickel and titanium alloys", Surf. Coat. Technol. 114 (1999) 156.   DOI   ScienceOn
6 H. Cho, D.M. Lee, J.H. Lee, K.H. Bang and B.W. Lee, "Thermal oxidation behavior of ceramic-coated Ni-Crbase superalloys", Surf. Coat. Tech. 202 (2008) 5625.   DOI   ScienceOn
7 B.W. Lee, J.C. Park, M.R. Kim, J. H. Koo, B.I. Kim and H. Cho, "The effect of TiCrN coating on high temperature stability of Inconel 617", J. Kor. Cryst. Grow. and Cryst. Tech. 21 (2011) 235.   DOI   ScienceOn
8 C.H. Jang, D.J. Lee and D.J. Kim, "Oxidation behavior of an Alloy 617 in very high-temperature air and helium environments", Int. J. Press. Vess. and Piping 85 (2008) 368.   DOI   ScienceOn
9 C. Cabet and F. Rouillard, "Corrosion of high temperature metallic materials in VHTR", J. Nucl. Mater. 392 (2009) 235.   DOI   ScienceOn
10 H. Cho and B.W. Lee, "High Temperature properties of surface-modified Hastelloy X alloy", J. Kor. Cryst. Grow. and Cryst. Tech. 22 (2012) 183.   DOI   ScienceOn
11 L.C. Olson, C. Luke, J.W. Ambrosek, K. Sridharan, M.H. Anderson, H. Mark and T.R. Allen, "Materials corrosion in molten LiF-NaF-KF salt", J. Fluorine Chem. 130 (2009) 67.   DOI   ScienceOn
12 P.F. Peterson, H. Zhao and G. Fukuda, "Comparison of molten salt and high-pressure helium for the NGNP intermediate heat transfer fluid", UCBTH-03-004 (2003).
13 F. Carre, P. Yvon and P. Chaix, "Innovative reactor systems and requirements for structural materials", OECD NEA NSC Workshop on Structural Materials for Innovative, Karlsruhe, Germany (2007).
14 J.W. Koger, "Evaluation of Hastelloy N alloys after nine years exposure to both a molten fluoride salt and air at temperatures from 700 to 560${^{\circ}C}$", ORN L-TM-4189 (1972).
15 I. Ozeryanaya, "Corrosion of metals by molten salts in heat-treatment processes", Met. Sci. Heat Treat. 3 (1985) 184.
16 H. Cho, K.H. Bang and B.W. Lee, "Thermal properties of the surface-modified Inconel 617", J. Kor. Cryst. Grow. and Cryst. Tech. 19 (2009) 298.
17 T. Watanabe, M. Kondo, T. Nagasaka and A. Sagara, "Corrosion characteristic of AlN, $Y_{2}O_{3}$, $Er_{2}O_{3}$ and$Al_{2}O_{3}$ in Flinak for molten salt blanket system", J. Plasma Fusion Res. 9 (2010) 342.