Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2010.20.3.133

Fabrication of various carbon nanostructures by using different catalysts  

Choi, Kang-Ho (Materials Processing Devision, Korea Institute of Materials Science)
Yoo, In-Joon (Materials Processing Devision, Korea Institute of Materials Science)
Lee, Hee-Soo (Pusan National Univ.)
Lee, Kyu-Hwan (Materials Processing Devision, Korea Institute of Materials Science)
Lim, Dong-Chan (Materials Processing Devision, Korea Institute of Materials Science)
Abstract
Carbon fiber has many potential applications in a wide array of fields of solar cell, fuel cell, batteries, and polymer matrix composites due to an exceptional mechanical properties and chemical stability. In this study, the effects of catalysts on the property of carbon nanostructures grown on the carbon fiber were systematically investigated. The surface treatment of carbon fiber and catalysts synthesis for carbon nanostructures growth were carried out by one-pot ELP method and thermal CVD, respectively. The surface morphology and crystal structure of carbon nanostructures were examined using a field emission scanning electron microscope and transmission electron microscope. Depending on the type of catalysts and the molar ratio, various types of carbon nanostructures like carbon nanotube, carbon nanofilament, carbon nanospring and etc. were synthesized on the surface of carbon fibers surface.
Keywords
Thermal CVD; ELP; Carbon nanostructures; Carbon fiber;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 W. Wunderlich, "Growth model for plasma-CVD growth of carbon nano-tubes on Ni-sheets", Diamond & Related Materials 16 (2007) 369.   DOI   ScienceOn
2 A.M. Pantano, D. Parks and M.C. Boyce, "Mechanics of deformation single- and multi-wall carbon nano-tubes", Journal of the Mechanics and Physcis of Solids 52 (2004) 789.   DOI   ScienceOn
3 S. Iijima, "Helical microtubules of graphitic carbon", Nature 354 (1991) 56.   DOI
4 Z. Zhang, D.H.C. Chua, Y. Gao, Y. Zhang, Z. Tang, B.K. Tay, T. Feng, Z. Sun and Y. Chen, "Field-emission properties of carbon nanotubes grown using Cu-Cr catalysts", Journal of Vacuum Science and Technology 27 (2009) 41.   DOI
5 K. Otsuka, H. Ogihara and S. Takenaka, "Decomposition of methane over Ni catalysts supported on carbon fibers formed from different hydrocarbons", Carbon 41 (2003) 223.   DOI   ScienceOn
6 S.P. Sharma and S.C. Lakkad, "Morphology study of carbon nanospecies grown on carbon fibers by thermal CVD technique", Surface & Coatings Technology 203 (2009) 1329.   DOI   ScienceOn
7 J. Li, C. Papadopoulos and J. Xu, "Nanoelectronics: Growing Y-junction carbon nanotubes", Nature 402 (1999) 253.
8 J.-M. Ting and R.-M. Liu, "Carbon nanowires with new microstructures", Carbon 41 (2003) 625.
9 Y. Li, B. Zhang, X. Xie, J. Liu, Y. Xu and W. Shen, "Novel Ni catalysts for methane decomposition to hydrogen and carbon nanofibers", Journal of Catalysis 238 (2006) 412.   DOI   ScienceOn
10 S. Takenaka, S. Kobayashi, H. Ogihara and K. Otsuka, "$Ni/SiO_{2}$ catalyst effective for methane decomposition into hydrogen and carbon nanofiber", Journal of Catalysis 217 (2003) 79.
11 B. Gan, J. Ahn, Q. Zhang, Rusli, S.F. Yoon and J. Yu, "Y-junction carbon nanotubes grown by in situ evaporated copper catalyst", Chemical and Physics Letters 333 (2001) 23.   DOI   ScienceOn
12 T. Hashishin and J. Tamaki, "Au-Pd catalyzed growth of carbon nanofibers mat", Materials Chemistry and Physics 111 (2008) 54.   DOI   ScienceOn
13 Z.Y. Juang, J.F. Lai, C.H. Weng, J.H. Lee, H.J. Lai, T.S. Lai and C.H. Tsai, "On the kinetic of carbon nanotube growth by thermal CVD method", Diamond & Related Materials 13 (2004) 2140.   DOI   ScienceOn
14 T. Hirata, N. Sakate, G.H. Jeong, T. Kato, R. Hatakeyama, K. Motomiya and L. Tohji, "Magnetron-type radio-frequency plasma control yielding vertically well-aligned carbon nanotube growth", Applied Physics Letters 83 (2003) 1119.   DOI   ScienceOn
15 P. Delhaes, M. Couzi, M. Trinquecoste, J. Dentzer, H. Hamidou and C. Vix-Guterl, "A comparison between Raman spectroscopy and surface characterizations of multiwall carbon nanotubes", Carbon 44 (2006) 3005.   DOI   ScienceOn
16 M. Meyyappan, L. Delzeit, A. Cassell and D. Hash, "Carbon nanotube growth by PECVD: a review", Plasma Sources Science and Technology 12 (2003) 205.   DOI   ScienceOn
17 A.G. Nasibulin, P.V. Pikhitsa, P. Queipo, M. Choi and E.I. Kauppinen, "Investigations of mechanism of carbon nanotube growth", Physica Status Solidi (B) Basic Research 13 (2006) 3095.
18 D. Takagi, Y. Kobayashi and Y. Homma, "Carbon nano-tube growth from diamond", Journal of the America Chemical Society 131 (2009) 6922.   DOI   ScienceOn
19 N.K. Chang and S.H. Chang, "High-yield synthesis of carbon nanocoils on stainless steel", Carbon 46 (2008) 1091.   DOI   ScienceOn
20 Y. Fernandez, B. Fidalgo, A. Dominguez, A. Arenillas and J.A. Menendez, "Carbon nanofilament synthesis by the decomposition of $CH_{4}/CO_{2}$ under microwave heating", Carbon 45 (2007) 1696.   DOI   ScienceOn
21 S.K. Pillai, L. Matlhoko, C. Arendse, S. Sinha Ray and M. Moodley, "The use of calcination in exposing the entrapped Fe particles from multi-walled carbon nanotubes grown by chemical vapor deposition", Applied Physics A: Materials Science and Processing 94 (2009) 585.   DOI   ScienceOn
22 M.-F. Fiawoo, A.-M. Bonnot, V. Jourdain, T. Michel, M. Picher, R. Arenal, J. Thibault-Pénisson and A. Loiseau, "Substrate preparation techniques for direct investigation by TEM of single wall carbon nanotubes grown by chemical vapor deposition", Surface Science 603 (2009) 1115.   DOI   ScienceOn
23 Z. Zhang, M. Shakerzadeh, B. Tay, X. Li, C. Tan, L. Lin, P. Guo, T. Feng and Z. Sun, "Fabrication of aligned carbon nanotubes on Cu catalyst by dc plasma-enhanced catalytic decomposition", Applied Surface Science 255 (2009) 6404.   DOI   ScienceOn
24 N. Zhao, Q. Cui, C. He, C. Shi, J. Li, H. Li and X. Du, "Synthesis of carbon nanostructures with different morphologies by CVD of methane", Materials Science and Engineering A 460-461 (2007) 255.   DOI   ScienceOn
25 R.L. Vander Wal and L.J. Hall, "Carbon nanotube synthesis upon stainless steel meshes", Carbon 41 (2003) 659.   DOI   ScienceOn
26 V. Mart Lnez-Hansen, N. Latorre, C. Royo, E. Romeo, E. Garc La-Bordeje and A. Monzo, "Development of aligned carbon nanotubes layers over stainless steel mesh monoliths", Catalysis Today 147 (2009) 71.   DOI   ScienceOn
27 S.I. Yang, "Structural study using ultrahigh resolution carbon nanotube AFM probe tips", Journal of the Korean Chemical Society 49 (2005) 517.   DOI   ScienceOn
28 C.E. Baddour, F. Fadlallah, D. Nasuhoglu, R. Mitra, L. Vandsburger and J.-L. Meunier, "A simple thermal CVD method for carbon nanotube synthesis on stainless steel 304 without the addition of an extermal catalyst", Carbon 47 (2009) 313.   DOI   ScienceOn
29 A. AgIral, L. Lefferts and J.G.E. Gardeniers, "In situ CVD of carbon nanofibers in a microreactor", Catalysis Today 150 (2010) 128.   DOI   ScienceOn
30 Z.P. Huang, J.W. Wu, Z.F. Ren, J.H. Wang, M.P. Siegal and P.N. Provencio, "Growth of highly oriented carbon nanotubes by plasma-enhanced hot filament chemical vapor deposition", Applied Physics Letters 73 (1998) 3845.   DOI   ScienceOn
31 A.A. Puretzky, D.B. Geohegan, X. Fan and S.J. Pennycook, "Dynamics of single-wall carbon nanotube synthesis by laser vaporization", Applied Physics A: Materials Science and Processing 70 (2000) 153.   DOI   ScienceOn
32 Q. Zhang, S.F. Yoon, J. Ahn, B. Gan, Rusli, M.B. Yu, L.K. Cheah and X. Shi, "Field emission from carbon nanotubes produced using microwave plasma assisted CVD", International Journal of Modern Physics B 14 (2000) 289.   DOI   ScienceOn
33 A.C. Dupuis, "The catalyst in the CCVD of carbon nanotubes- a review", Progress in Materials Science 50 (2005) 929.   DOI   ScienceOn
34 J.Y. Kim, Y. Jo, S.-K. Kook, S. Lee and H.C. Choi, "Synthesis of carbon nanotube supported Pd catalysts and evaluation of their catalytic properties for C-C bond forming reactions", Journal of Molecular Catalysis A 323 (2010) 28.   DOI   ScienceOn
35 D.D. Edie, "The effect of processing on the structure and properties of carbon fibers", Carbon 36 (1998) 345.   DOI   ScienceOn
36 H. Takikawa, M. Yatsuki, T. Sakakibara and S. Itoh, "Carbon nanotubes in cathodic vacuum arc discharge", Journal of Physics D: Applied Physics 33 (2000) 826.   DOI   ScienceOn