Browse > Article

The properties of a low expansion glass ceramics of $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system  

Kim, Bok-Hee (Div. of Advanced Materials Engineering, Chonbuk National University)
Ko, Jung-Hoon (Dept. of Hydrogen and Fuel Cells Engineering, Speciallized Graduate School, Chonbuk National University)
Nam, O-Jung (Dept. of Hydrogen and Fuel Cells Engineering, Speciallized Graduate School, Chonbuk National University)
Kang, Woo-Jin (Div. of Advanced Materials Engineering, Chonbuk National University)
Lee, Chang-Hoon (GAT Co. Ltd.)
Abstract
The glass-ceramic of the $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system was investigated to develop the low thermal expansion materials. The glass of this system was heat treated at $775^{\circ}C$ for 2 h for nucleation and subsequently at $825{\sim}900^{\circ}C$ for 2 h for crystallization. The crystal structure of the glass-ceramic of this system was a single phase of $\beta$-quartz solid solution($Li_{x}Al_{x}Si_{1-x}O_{2}$). The thermal expansion of the glass-ceramic showed $4.40{\times}10^{-7}{\sim}1.33{\times}10^{-6}K^{-1}$ between $25{\sim}300^{\circ}C$ and $1.56{\times}10^{-6}{\sim}2.53{\times}10^{-6}K^{-1}$ between $25{\sim}800^{\circ}C$, higher than lower temperature range. The mechanical strength remained almost same at around high 110 MPa with heating temperature changes.
Keywords
Glass-ceramic; $Li_{2}O-Al_{2}O_{3}-SiO_{2}$; Low thermal expansion; Nucleation; Crystallization; Mechanical strength; Solid solution;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Y.-M. Sung, S.A. Dunn and J.A. Koutsky, "The effect of boria and titania addition on the crystallization and sintering behavior of $Li_2O-Al_2O_3-4SiO_2$ glass", J. Eur. Ceram. Soc. 14 (1994) 455   DOI   ScienceOn
2 J.J. Shyu and H.H. Lee, "Sintering, crystallization and properties of B2O3/P2O5 doped Li2OAl2O34SiO2 glassceramics", J. Am. Ceram. Soc. 78(8) (1995) 2161   DOI   ScienceOn
3 P.W. Mcmillan, "Glass-ceramic, academic", London (1979) 81
4 R. Cioffi, P. Pernice, A. Aronn and A. Marotta, "Nucleation and crystal growth in a fly ash derived glass", J. Mater. Sci. 28 (1993) 6591   DOI   ScienceOn
5 T. Nagakane, Y. Himei, N. Kitamura, J. Nishii, K. Fukumi, A. Sakamoto and K. Hirao, "Optical properties of Li2O-Al2O3-SiO2 glass-ceramic crystallized under high pressure", J. Ceram. Soc. of Japan 114(2) (2006) 180   DOI   ScienceOn
6 G.H. Beall and D.A. Duke, "Transparent glass ceramic", J. Mat. Sci. 4 (1969) 340   DOI
7 G.H. Beall and L.R. Pinckey, "Nanophase glass-ceramics", J. Am. Ceram. Soc. 82 (1999) 5   DOI   ScienceOn
8 Y.W. Park and Y.W. Kim, "A study on the transparent glass-ceramics on Al2O3-SiO2 system", J. of the Korean Ceramic Society 29 (1992) 223   과학기술학회마을
9 G. Partridge, "An overview of glass-ceramics: Part 1- development and principal bulk applications", Glass Technology 35(3) (1994) 116   ScienceOn
10 C. Suryanarayana and M. Grant Norton, "X-Ray diffraction -A practial approach", Plenum Press·New York and London (1998) 212
11 W.D. Kingery, H.K. Bowen and D.R. Uhlmann, "Introduction to ceramics", 2nd ed. John Wiley & Sons (1976) 361