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The synthesis and crystal structure of $[({\eta}^5-Cp)Co]_2$(1,2-S,S-o-Carborane) $(C_{12}H_{20}B_{10}S_2Co_2)$  

Cho, Sung-Il (Department of Chemical Engineering, University of Seoul)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.18, no.2, 2008 , pp. 62-67 More about this Journal
Abstract
An Organometallic compound, $C_{12}H_{20}B_{10}S_2Co_2$, was synthesized from o-carborane, $Cp^*Co(S_2B_2B_{10}H_{10})$ and $BH_3{\cdot}THF$. The molecular structure of this complex has been determined by X-ray diffraction. Crystallographic data: monoclinic, space group Cc, a=15.981(4) ${\AA}$, b=15.478(17) ${\AA}$, c=12.0562(17) ${\AA}$, ${\beta}=115.063(16)^{\circ}$, Z=4, V=9683(4) ${\AA}^3$. The structure was solved by direct methods and refined by full-matrix leat-squares methods to give a model with a reliability factor R = 0.0630 for 9948 reflections.
Keywords
Crystal structure$C_{12}H_{20}B_{10}S_2Co_2$; Reliability factor; Direct methods; Full-matrix leat-squares; o-Carborane; Monoclinic; Cyclo-pentadienyl; ORTEP; X-Ray diffraction;
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