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Fabrication and sintering of nano $TiN_x$ and its composites  

Kim, Dong-Sik (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Kim, Sung-Jin (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Rahno, Khamidova (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Park, Sung-Bum (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Park, Seung-Sik (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Lee, Hye-Jeong (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Lee, Sang-Woo (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Cho, Kyeong-Sik (Department of Information and Nano Materials, Kumoh National Institute of Technology)
Woo, Heung-Sik (Department of Safety Engineering, DongEuk University)
Ahn, Joong-Ho (Advenced Materials Engineering, Andong National University)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.16, no.3, 2006 , pp. 101-105 More about this Journal
Abstract
We fabricated the nano $TiN_x$ by making of reaction between titanium powder and $Si_3N_4$ during planetary milling. The $TiN_x$ powder was sintered by spark plasma sintering machine after mixing with 50 wt% of titanium powder, and the sintered body was heat-treated at $850^{\circ}C$ in order to investigate its hardness property at the elevated temperature. We analyzed crystal structure by XRD. We observed the peaks of $TiN_{0.26}$ and TiN after 10 hours milling, and we observed TiN peak mainly after 20 hours milling. The reacted particle size distribution was investigated by FE-SEM. Increase of milling time, the size of reacted particles was decreased and the $10{\sim}20nm$ size of $TiN_x$ on the surface of titanium and $TiN_x$ was observed after 20 hours milling. The micro-Vickers hardness of mixed sintered body was about $1050kgf/mm^2$.
Keywords
$Nano-TiN_x$; Planetary milling; Composites; Hardness; Reaction; Size reduction;
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  • Reference
1 J.H. Lee, Y.S. Jang, H.C. Park and K.D. Oh, 'Preparation of fine titanium nitride powders from titanium trichloride', 27 (1990) 916
2 N.Y. Kim, Y.B. Son, J.H. Oh, C.K. Hwangbo and M.C. Park, '$TiN_{x}$ layer as an antireflection and antistatic coating for display', Surface and Coatings Technology 128 (2000) 156   DOI   ScienceOn
3 J. Zbiral, a Jangg and G. Korb, 'Influences of heattreatments on the constitution and the recrystallization response of the Y'-strengthened ODS-Ni-base alloy PM 3030', Metall. Sci. Forum, Trans Tech. Publications, Zurich 88-90 (1992) 18
4 J.S. Benjamin and RD. Schelleng, 'Temperature alloys: theory design', Metall Trans. 12A (1981) 1827
5 J.S. Benjamin, 'Dispersion strenghened superalloys by mechanical alloying', Metall. Trans. 1 (1970) 2943
6 K. Aoki, A. Memezawa and T. Masumoto, 'Nitrogen induced amorphization of Ti-Zr powders during mechanical alloying', Appl. Phys. Lett. 61 (1992) 1037   DOI
7 C.H. Lee, M. Mori, Fukunaga and U. Mizutani, 'Structural evidence for the amorphization of mechanically alloyed Cu-Ta powders studied by neutron diffraction and EXAFS', Mat. Sci. Forum 88 (1992) 399
8 A.H. Claure and J.J. de Barbadillp, Solid State Powder Processing 3-19 (TMS, 1990)
9 J.S. Benjamin and MJ. Bamford, 'Dispersion strengthned aluminum made by mechanical alloying', Metall Trans. 8A (1977) 130l
10 J. Rivory, J.M. Behaghel, S. Berthier and J. Lafait, 'Optical properties of substoichiometric $TiN_{x}$', Thin Solid Films 78 (1981) 161   DOI   ScienceOn
11 Y. Ogino, S. Murayama and T. Yamasaki, 'Influence of milling atmosphere on amorphization of chromium and Cr-Cu powders by ball milling', J. Less-Common Metals 168 (1991) 221   DOI   ScienceOn
12 G.B. Schaffer and P.G. McCormick, 'A nanocrystalline mixture of intermetallic compounds by mechanical alloying', Metall. Trans. A23 (1992) 1285
13 K. Sakurai, C.H. Lee, N. Kuroda, T. Fukunaga and U. Mizutani, 'Nitrogen effect in mechanical alloying of immiscible Cu-V : extended X-ray absorption fine structure study', J. Appl. Phys. 75 (1994) 7752   DOI   ScienceOn
14 SJ. Kim, D.S. Kim, R. Khamidova, S.B. Park, W.I. Gwon, M.H. Kim, H.S. Woo, J.H. Ahn, 'Fabrication of TiN by planetary milling', Journal of the Korean Crystal Growth and Crystal Technology 15 (2005) 104