Browse > Article

Effects of post-annealing and seeding layers on electrical properties of PLT thin films by MOCVD using ultrasonic spraying  

이진홍 (경북대학교 무기재료공학과)
김기현 (경북대학교 무기재료공학과)
박병옥 (경북대학교 무기재료공학과)
Abstract
$(Pb_{1-x}La_x)TiO_3$ (x = 0.1) thin films were prepared on ITO-coated glass substrates by metal organic chemical vapor deposition using ultrasonic spraying. Effects of the post-annealing and the seeding layer on crystallization, microstructures and electrical properties of thin films were investigated. Dielectric constants of films increased due to the modification of crystallization and the changing of a surface morphology by applying the post-annealing. In addition, as the application of PT seed- ing layer offered nucleation sites to PLT thin films, electrical properties of films were enhanced by the increase of crys-tallinity and grain size. The dielectric constant of the films post-heated for 60 min and with a seeding layer was 213 at 1 kHz.
Keywords
PLT thin films; MOCVD using ultrasonic spraying; Post-annealing; Seeding layer;
Citations & Related Records
연도 인용수 순위
  • Reference
1 T. Masuda, Y. Miyaguchi, M. Tanimura, Y. Nishioka, K. Suu and N. Tani, 'Development of PZT Sputtering Method for Mass-production', Appl. Surf. Sci. 169 (2001) 539
2 C. Guerrero, C. Ferrater, J. Roldan, V. Trtik, F. Sanchez and M. Varela, 'Epitaxial Ferroelelctric $PbZr_{X}Ti_{1-X}O_{3}$ Thin Films for Non-volatile Memory Applications', Microelectronics Reliability 40 (2000) 671
3 H. Funakubo, K. Nagashima, K. Shinozaki and N. Mizutani, 'Comparison of Deposition Behavior of $Pb(Zr,Ti)O_{3}$ Films and its End-member-oxide Films Prepared by MOCVD', Thin Solid Films 368 (2000) 261
4 L. Shi, S.B. Krupanidhi and G.H. Haertling, 'Development of Ferroelectric $Pb(Zr_{X}Ti_{1-X})O_{3}$ Thin Films by Metallo-organic Decomposition Process and Rapid Thermal Annealing', Integr, Fenoelectrics 1 (1992) 111
5 J.K. Kim, N.K. Kim and B.O. Park, 'Effect of Ultrasound on Perovskite Pahse Developments, Microstructure, and Dielectric Properties of Sol-gel-processed $PbTiO_{3}$ Thin Films', Mater. Res. Bull. 35 (2000) 4995
6 J.K. Kim, N.K. Kim and B.O. Park, 'Effects of Ultra-sound on Microstructure and Electrical Properties of $Pb(Zr_{0.5}Ti_{0.5})O_{3}$ Thin Films Prepared by Sol-gel Method', Mater. Lett. 39 (1999) 28
7 J.H. Lee, S.W. Jung, N.K. Kim and B.O. Park, 'Electrical And Optical Properties Of $(Pb_{0.9}la_{0.1})tio_{3}$ Films Prepared by the Sol-gel Method with Ultrasound Application', Thin Solid Films 410 (2002) 38
8 N.M. Tallan, 'Electlical Conductivity in Ceramics and Glass' (1983) 463
9 J.H. Lee, Y.H. Kim, S.H. Lee and B.O. Park, 'Preparation and Properties of $PbTiO_{3}$ Thin Films by MOCYD Using Ultrasonic Spraying', J. Kor. Cryst. Growth 10, 3 (2000) 205
10 J.S. Lee, C.J. Kim, D.S. Yoon, W.J. Lee and K.S. No, 'Effects of seeding layer on orientation and phase formation of Sol-gel Derived Lanthanum-modified Lead Zirconate Titanate Films of Glass', Jpn. J. Appl. Phys. Pt. 1,34, 4A (1995) 1947
11 W. Liu and W. Zhu, 'Preparation and Orientation Control of $Pb_{1t}(Zr_{0.3}Ti_{0.7})O_{3}$ Thin Films by a Modified Solgel Process', Mater. Lett. 46 (2000) 239