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http://dx.doi.org/10.3740/MRSK.2012.22.1.024

Effect of Annealing in a Nitrogen Atmosphere on the Properties of In2O3 Films Deposited with RF Magnetron Sputtering  

Kong, Young-Min (School of Materials Science and Engineering, University of Ulsan)
Lee, Young-Jin (School of Materials Science and Engineering, University of Ulsan)
Heo, Sung-Bo (School of Materials Science and Engineering, University of Ulsan)
Lee, Hak-Min (School of Materials Science and Engineering, University of Ulsan)
Seo, Min-Su (School of Materials Science and Engineering, University of Ulsan)
Kim, Yu-Sung (R&D Division, New Optics LTD.)
Kim, Dae-Il (School of Materials Science and Engineering, University of Ulsan)
Publication Information
Korean Journal of Materials Research / v.22, no.1, 2012 , pp. 24-28 More about this Journal
Abstract
$In_2O_3$ films were deposited by RF magnetron sputtering on a glass substrate and then the effect of post deposition annealing in nitrogen atmosphere on the structural, optical and electrical properties of the films was investigated. After deposition, the annealing process was conducted for 30 minutes at 200 and $400^{\circ}C$. XRD pattern analysis showed that the as deposited films were amorphous. When the annealing temperature reached 200-$400^{\circ}C$, the intensities of the $In_2O_3$ (222) major peak increased and the full width at half maximum (FWHM) of the $In_2O_3$ (222) peak decreased due to the crystallization. The films annealed at $400^{\circ}C$ showed a grain size of 28 nm, which was larger than that of the as deposited amorphous films. The optical transmittance in the visible wavelength region also increased, while the electrical sheet resistance decreased. In this study, the films annealed at $400^{\circ}C$ showed the highest optical transmittance of 76% and also showed the lowest sheet resistance of $89{\Omega}/\Box$. The figure of merit reached a maximum of $7.2{\times}10^{-4}{\Omega}^{-1}$ for the films annealed at $400^{\circ}C$. The effect of the annealing on the work-function of $In_2O_3$ films was considered. The work-function obtained from annealed films at $400^{\circ}C$ was 7.0eV. Thus, the annealed $In_2O_3$ films are an alternative to ITO films for use as transparent anodes in OLEDs.
Keywords
$In_2O_3$; magnetron sputtering; nitrogen atmosphere; annealing; figure of merit;
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Times Cited By KSCI : 5  (Citation Analysis)
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