Browse > Article
http://dx.doi.org/10.3740/MRSK.2003.13.8.537

Preparations of (Yl-xGdx)2O3:Eu3+ Phosphors Particles by. Solvothermal Synthesis Using the 2-Methoxy Ethanol  

Shin, Su-Cheol (Department of Industrial chemistry, Dankook University)
Cho, Tae-Hwan (Department of Industrial chemistry, Dankook University)
Publication Information
Korean Journal of Materials Research / v.13, no.8, 2003 , pp. 537-542 More about this Journal
Abstract
($Y_{l-x}$ $Gd_{x}$ )$O_2$$_3$: $Eu^{ 3+}$ red phosphors were prepared with the solvothermal synthesis using the 2-methoxy-ethanol solvents and the emission intensity was investigated that applied with the 254 nm wavelength and the maximum excitation wavelength for energy source. The used solvents for the solvothermal synthesis were made of nitrate salt solutions of Y, Gd and Eu. These solutions dropped in autoclave have be reacted with the solvothermal synthesis at $200^{\circ}C$ for 5hrs and the red phosphors prepared here in were showed the pure cubic phase after annealing at $1000∼1200^{\circ}C$. The brightness of ($Y_{l-x}$ $Gd_{x}$)$_2$$O_3$: $Eu^{3+}$ phosphors particles was increased as an increase of Gd ratio. The maximum excitation wavelengths of ($Y_{l-x}$ $Gd_{x}$ )$_2$$O_3$: $Eu^{3+}$ / phosphors particles were increased according to increasing Gd ratio from 253 nm to 259 nm wavelength. The maximum emission intensity of $Gd_2$$O_3$: $Eu^{3+}$ (Y/Gd = 1/0) phosphors particles under UV 259 nm was found to be higher than the commercial product of $Y_2$$O_3$: $Eu^{3+}$ phosphors.
Keywords
solvothermal synthesis; red phosphors; photoluminescence; metal oxides.;
Citations & Related Records
연도 인용수 순위
  • Reference
1 /
[ V.Pelova;K.Kynev;Tz.Piperov ] / Cryst. Res. Technol.   DOI   ScienceOn
2 /
[ J.Silver;M.I.Martinea-Rubio;T.G.Ireland;G.R.Fern;R.J.Withnall ] / Phys. Chem. B   DOI   ScienceOn
3 B. Li, Y. Xie, H. Su, Y. Qian and X. Liu, Solid State Ionics, 120, 251 (1999)   DOI   ScienceOn
4 Z. Han, N. Guo, F. Li, W. Zhang, H. O. Zhao and Y. Qian, Mater. Lett., 48(2), 99 (2001)   DOI   ScienceOn
5 J. Yang, X. L. Yang, S. H. Yu, X. M. Liu and Y. T. Qian, Mater. Res. Bull., 35(9), 1509 (2000)   DOI   ScienceOn
6 Z. H. Han, Y. P. Li, H. Q. Zhao, S. H. Yu, X. L. Yin and Y. T. Qian, Mater. Lett., 44, 366 (2000)   DOI   ScienceOn
7 C. An, K. Tang, G. Shen, C. Wang, G. Yang, B. Hai and Y. Qian, J. Crystal Growth, 244, 333 (2002)   DOI   ScienceOn
8 S. H. Yu, J. Yang, Y. T. Qian and M. Yoshimura, Chem. Phys. Lett., 361(5-6), 362 (2002)   DOI   ScienceOn
9 H. S. Roh, Y. C. Kang and S. B. Park, J. Colloid Interface. Sci. 228, 195 (2000)   DOI   ScienceOn
10 Y. D. Jiand, Z. L. Wang, F. Zhang, H. G. Paris and C. J. Summers, J. Mater. Res., 75, 128 (1998)
11 G. Y. Hong, B. S. Jeon, Y. K. Yoo and J. S. Yoo, J. Electrohem. Soc., 148(11), H161 (2001)   DOI   ScienceOn
12 Joint committee for powder diffraction standards, JCPDS Card No.411105
13 Joint committee for powder diffraction standards, JCPDS Card No.120797
14 E. T. Goldburt, B. Kulkarni, R. Bhargava, J. Taylor and M. Libera, J. Lumin., 190, 72 (1997)
15 Y. C. Kang, I. W. Lenggoro, K. Okuyama and S. B. Park, J. Electrohem. Soc., 146(3), (1999) 1227   DOI   ScienceOn
16 P. Maestro, D. Huguenin, A. Seigneurim, F. P. L. Deneuve and J. F. Berar, J. Electrohem. Soc., 139(5), 1479 (1992)   DOI
17 R. N. Bhargava, D. Gallagher, X. Hong and A. Nurmikio, Phys. Rev. Lett., 72(3), 416 (1994)   DOI   ScienceOn
18 J. Silver, M. I., Martinea-Rubio, T. G., Ireland, G. R. Fern and R. J. Withnall, Phys. Chem. B, 105, 9107 (2001)   DOI   ScienceOn
19 X. Shangda, T. Ye, Z. Guiwen and Z. Weiping, Mater. Res. Bull., 32(5), 501 (1997)   DOI   ScienceOn
20 G. Blasse and B. C. Grabmaier, 'Luminescent Materials,' p.16, 41 Springer-Verlag, New York, (1994)
21 D. S. Kim and R. Y. Lee, J. Mater. Sci., 35, 4777 (2000)   DOI   ScienceOn
22 V. Pelova, K. Kynev and Tz. Piperov, Cryst. Res. Technol., 33, 125 (1998)   DOI
23 H. S. Roh, Y. C. Kang and S. B. Park, J. Colloid Interface. Sci., 228, 195 (2000)   DOI   ScienceOn
24 C. D. Vetch, J. Mater. Sci. Eng., 18, 1 (1993)   DOI   ScienceOn
25 L. D. Sun, J. Yao, C. H. Liu, C. S. Liao and C. H. Yan, J. Lumin., 87-89, 447 (2000)   DOI   ScienceOn