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http://dx.doi.org/10.5857/RCP.2016.5.2.16

E-beam Irradiated Fragmentation of Thio-Alkyne Cobaltcarbonyl Complex in Gas Phase as Alkyne Precursor  

Lee, Young Bae (Department of Bio & Chemical Engineering, Hongik University)
Hwang, Kwang-Jin (Department of Bio & Chemical Engineering, Hongik University)
Publication Information
Rapid Communication in Photoscience / v.5, no.2, 2016 , pp. 16-17 More about this Journal
Abstract
Arylalkyne cobalt complexes 5, 6 were prepared and irradiated with e-beam to study their fragmentation focused in alkyne formation. Thioaryl complex 6 showed facile CO ligand release and generated parent alkyne in 89% relative intensity. Meanwhile, hydroxyaryl complex 5 gave alkyne in 6% relative intensity.
Keywords
Thioalkyne; cobalt-alkyne complex; e-beam; fragmentation;
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