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http://dx.doi.org/10.5857/RCP.2015.4.4.86

E-beam Irradiation of Diyne-Cobaltcarbonyl Complexes for the Generation of Conjugated Alkyne in Gas Phase  

Choi, Jeong-Chul (Department of Bio & Chemical Engineering, Hongik University)
Hwang, Kwang-Jin (Department of Bio & Chemical Engineering, Hongik University)
Publication Information
Rapid Communication in Photoscience / v.4, no.4, 2015 , pp. 86-87 More about this Journal
Abstract
Substituted butadiyne cobalt complexes 1, 2 were prepared and placed on the e-beam to study the fragmentation focused on diyne generation, in MS spectrometer. Phenyl or methyl substituted cobalt complexes generated the corresponding diyne with 100, 30% relative intensities under e-beam irradiation in gas phase.
Keywords
conjugated alkyne; diyne; cobalt-alkyne complex; e-beam;
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