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http://dx.doi.org/10.5857/RCP.2015.4.1.22

Synthesis, Characterizations, and Intramolecular Quenching Behavior of an Axially-Linked Trinuclear Molecular Wire Containing Ruthenium(II) Porphycenes  

Abe, Masaaki (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
Ashigara, Shiho (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
Okawara, Toru (Department of Materials Chemistry and Chemical Engineering, National Institute of Technology, Kitakyushu College)
Hisaeda, Yoshio (Center for Molecular Systems (CMS), Kyushu University)
Publication Information
Rapid Communication in Photoscience / v.4, no.1, 2015 , pp. 22-24 More about this Journal
Abstract
A new trinuclear complex $[Ru(TPrPc)(CO)]_2[Ru(pytpy)_2](PF_6)_2$ (TPrPc = 2,7,12,17-tetra-n-propylporphycenato dianion and pytpy = 4'-(4-pyridyl)-2,2':6',2"-terpyridine) has been synthesized and characterized as the first example of a discrete molecular wire containing metalloporohycenes as a building block. The trinuclear complex shows multiple-step redox behavior in 0.1 M n-$Bu_4NPF_6$-dichloromethane. The mononuclear $[Ru(pytpy)_2]^{2+}$ precursor shows emission at 640 nm (deaerated acetone, 298 K) upon illumination at the metal-to-ligand charge transfer (MLCT) band at 495 nm, but the trinuclear molecular wire is found to be non-emissive upon photoexcitation at the central $[Ru(pytpy)_2]^{2+}$ entity, indicating an efficient quenching ability of the axially-linked, ruthenium(II)-porphycene chromophores in an intramolecular fashion.
Keywords
porphycene; ruthenium; molecular wire; cyclic voltammetry; luminescence;
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1 Vogel, E.; Kocher, M.; Schmickler, H.; Lex, J. Angew. Chem. Int. Ed. Engl. 1986, 25, 257-259.   DOI
2 Vogel, E.; Balci, M.; Pramod, K.; Koch, P.; Lex, J.; Ermer, O. Angew. Chem. Int. Ed. Engl. 1987, 26, 928-931.   DOI
3 D. Sanchez-GarciaJ. L. Sessler, Chem. Soc. Rev. 2008, 37, 215-238.   DOI
4 Waluk, J. Acc. Chem. Res. 2006, 39, 945-952.   DOI   ScienceOn
5 Czerski, I.; Listkowski, A.; Nawrocki, J.; Urbanska, N.; Piwonski, H.; Sokolowski, A.; Pietraszkiewicz, O.; Pietraszkiewicz, M.; Waluk, J. J. Porphyrins Phthalocyanines 2012, 16, 589-602.   DOI   ScienceOn
6 Kumagai, T.; Hanke, F.; Gawinkowski, S.; Sharp, J.; Kotsis, K.; Waluk, J.; Persson, M.; Grill, L. Nature Chem. 2014, 6, 41-46.   DOI
7 Hayashi, T.; Nakashima, Y.; Ito, K.; Ikegami, T.; Aritome, I.; Suzuki, A. Hisaeda, Y. Org. Lett. 2003, 5, 2845-2848.   DOI   ScienceOn
8 Matsuo, T.; Tohi, Y.; Hayashi, T. J. Org. Chem. 2012, 77, 8946-8955.   DOI   ScienceOn
9 Okawara, T.; Abe, M.; Hisaeda, Y. Tetrahedron Lett. 2014, 55, 6193-6197.   DOI   ScienceOn
10 Fowler, C. J.; Sessler, J. L.; Lynch, V. M.; Waluk, J.; Gebauer, A.; Lex, J.; Heger, A.; Zuniga-y-Rivero, F.; Vogel, E. Chem. Eur. J. 2002, 8, 3485-3496.   DOI
11 Lo, W.-C.; Che, C.-M.; Cheng, K.-F.; Mak, T. C. W. Chem. Commun. 1997, 1205-1206.
12 Li, Z.-Y.; Huang, S.; Che, C.-M. Inorg. Chem. 1992, 31, 2670-2672.   DOI
13 Okawara, T.; Abe, M.; Shimakoshi, H.; Hisaeda, Y. Bull. Chem. Soc. Jpn. 2011, 84, 718-728.   DOI   ScienceOn
14 Hasegawa, J.; Takata, K.; Miyahara, T.; Neya, S.; Frisch, M. J.; Nakatsuji, H. J. Phys. Chem. A 2005, 109, 3187-3200.   DOI   ScienceOn
15 Richert, C.; Wessels, J. M.; Mueller, M.; Kisters, M.; Benninghaus, T.; Goetz, A. E. J. Med. Chem. 1994, 37, 2797-2807.   DOI   ScienceOn
16 Bonnett, R. Chem. Soc. Rev. 1995, 24, 19-33.   DOI
17 Stockert, J. C.; Canete, M.; Juarranz, A.; Vallanueva, A.; Horobin, R. W.; Borrell, J. I.; Teixido, J.; Nonell, S. Curr. Med. Chem. 2007, 14, 997-1036.   DOI   ScienceOn
18 Matsuo, T.; Dejima, H.; Hirota, S.; Murata, D.; Sato, H.; Ikegami, T.; Hori, H.; Hisaeda, Y.; Hayashi, T. J. Am. Chem. Soc. 2004, 126, 16007-16007.   DOI   ScienceOn
19 Hayashi, T.; Okazaki, K.; Urakawa, N.; Shimakoshi, H.; Sessler, J. L.; Vogel, E.; Hisaeda, Y. Organometallics 2001, 20, 3074-3078.   DOI   ScienceOn
20 Costa, R. D.; Malig, J.; Brenner, W.; Jux, N.; Guldi, D. M. Adv. Mater. 2013, 25, 2600-2605.   DOI   ScienceOn
21 Brenner, W.; Malig, J.; Costa, R. D.; Guldi, D. M.; Jux, N. Adv. Mater. 2013, 25, 2314-2318.   DOI   ScienceOn
22 Nishihara, H. Chem. Lett. 2014, 43, 388-395.   DOI   ScienceOn
23 Imamura, T.; Fukushima, K. Coord. Chem. Rev. 2000, 198, 133-156.
24 Offord, D. A.; Sachs, S. B.; Ennis, M. S.; Eberspacher, T. A.; Griffin, J. H.; Chidsey, C. D. E.; Collman, J. P. J. Am. Chem. Soc. 1998, 120, 4478-4487.   DOI   ScienceOn
25 Okawara, T.; Abe, M.; Ashigara, S.; Hisaeda, Y. J. Porphyrins Phthalocianes, in press. DOI: 10.1142/S1088424614501120
26 de Biani, F. F.; Grigiotti, E.; Laschi, F.; Zanello, P.; Juris, A.; Prodi, L.; Chichak, K. S.; Branda, N. R. Inorg. Chem. 2008, 47, 5425-5440.   DOI   ScienceOn
27 Chichak, K.; Branda, N. R. Chem. Commun. 1999, 523-524.
28 Okawara, T.; Abe, M.; Shimakoshi, H.; Hisaeda, Y. Chem. Lett. 2008, 37, 906-907.   DOI   ScienceOn
29 Constable, Cargill Thompson, E. C. A. M. W. J. Chem. Soc., Dalton Trans. 1994, 1409-1418.
30 Constable, E. C.; Housecroft, C. E.; Cargill Thompson, A.; Passaniti, P.; Silvi, S.; Maestri, M.; Credi, A. Inorg. Chim. Acta 2007, 360, 1102-1110.   DOI   ScienceOn
31 Wagner, R. W.; Lindsey, J. S. J. Am. Chem. Soc. 1994, 116, 9759-9760.   DOI   ScienceOn
32 Harriman, A.; Odobel, F.; Sauvage, J.-P. J. Am. Chem. Soc. 1995, 117, 9461-9472.   DOI   ScienceOn