Browse > Article
http://dx.doi.org/10.13160/ricns.2019.12.4.101

Synthesis and Characterization of a Strontium Iron Fluoride Hydrated, Sr2Fe2F10(H2O)  

Kim, Sun Woo (Department of Chemistry Education, Chosun University)
Publication Information
Journal of Integrative Natural Science / v.12, no.4, 2019 , pp. 101-104 More about this Journal
Abstract
A hydrated strontium iron fluoride, Sr2Fe2F10(H2O) has been synthesized and characterized. The material was synthesized through mild hydrothermal reaction using an aqueous CF3COOH solution. The material exhibits a one-dimensional structure consisting of chains of corner-shared Fe3+F6 octahedra, isolated Fe3+F5(H2O) octahedra, chains of SrF10 polyhedra and isolated SrF8 polyhedra, respectively. Magnetic property measurements on Sr2Fe2F10(H2O) reveals an antiferromagnetic order at TN of ~2.5 K with a Weiss temperature (θ) of -61.51 K.
Keywords
Fluoride; Hydrothermal Synthesis; Crystal Structure; Antiferromagnet;
Citations & Related Records
연도 인용수 순위
  • Reference
1 J. B. Goodenough, "Theory of the Role of Covalence in the Perovskite-Type Manganites [La, M(II)]$MnO_3$", Physical Review, Vol. 100, No. 2, pp. 564-573, 1955.   DOI
2 P. W. Anderson, "New approach to the theory of superexchange interactions", Physical Review, Vol. 115, No. 1, pp. 2-13, 1959.   DOI
3 J. B. Goodenough, "Magnetism and the Chemical Bond", Interscience: New York, 1963.
4 S. W. Kim, R. Zhang, P. S. Halasyamani, and M. A. Hayward, "$K_4Fe_3F_{12}$: An $Fe^{2+}/Fe^{3+}$ Charge- Ordered, Ferrimagnetic Fluoride with a Cation-Deficient, Layered Perovskite Structure", Inorganic Chemistry, Vol. 54, Issue. 13, pp. 6647-6652, 2015.   DOI
5 H. Schmid, "Magnetoelectric Interaction Phenomena in Crystals", Kluwer: Dordrecht, 2004.
6 A. Tressaud, "Functionalized Inorganic Fluorides Synthesis, Characterization & Properties of Nanostructured Solids", John Wiley & Sons, Ltd, 2010.
7 P. Hagenmuller, "INORGANIC SOLID FLUORIDES: Chemistry and Physics", Academic Press, INC.: Orlando, 1985.
8 S. Fabbrici, E. Montanari, L. Righi, G. Calestani, and A. Migliori, "Charge order and tilt modulation in multiferroic $K_xM(II)_xM(III)_{1-x}F_3$ (0.4 ${\leq}$ x${\leq}$ 0.6) transition metal fluorides with tetragonal tungsten bronze structure", Chemisty of Materials, Vol. 16, Issue. 16, pp. 3007-3019, 2014.
9 N. A. Spaldin, and M. Fiebig, "The Renaissance of Magnetoelectric Multiferroics", Science, Vol. 309, Issue. 5733, pp. 391-392, 2005.   DOI
10 D. I. Khomskii, "Trend: Classifying multiferroics: Mechanisms and effects", Physics, Vol. 2, pp. 20, 2009.   DOI
11 J. F. Scott and R. Blinc, "Multiferroic magnetoelectric fluorides: why are there so many magnetic ferroelectrics?", Journal of Physics: Condensed Matter, Vol. 23, No. 11, pp. 113292, 2011.
12 J.-M. Le Meins, A. Hemon-Ribaud, and G. Courbion, "$Sr_2Fe_2F_{10}{\cdot}H_2O$, the first hydrated strontium iron(III) fluoride", Acta Crystallographica Section C: Crystal Structure Communication, Vol. C53, pp. 1165-1166, 1997.
13 S. W. Kim, S.-H. Kim, P. S. Halasyamani, M. A. Green, K. P. Bhatti, C. Leighton, H. Das, and C. J. Fennie, "$RbFe^{2+}Fe^{3+}F_6$. Synthesis, structure, and characterization of a new charge-ordered magnetically frustrated pyrochlore-related mixed-metal fluoride", Chemical Science, Issue. 3, pp. 741-751, 2012.   DOI
14 S. W. Kim, H. Y. Chang, and P. S. Halasyamani, "Selective Pure-Phase Synthesis of the Multiferroic $BaMF_4$ (M = Mg, Mn, Co, Ni, and Zn) Family", Journal of the American Chemical Society, Vol. 132, Issue. 50, pp. 17684-17685, 2010.   DOI