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http://dx.doi.org/10.13160/ricns.2016.9.4.255

Crystal Structure Analysis of N,N'-bis(3-chloro-2-methylsalicylidene)-1,4-butanediamine  

Sharmila, P. (Department of Physics, Presidency College)
Rajesh, R. (Department of Chemistry, Pondicherry University)
Venkatesan, R. (Department of Chemistry, Pondicherry University)
Ganapathy, Jagadeesan (Department of Physics, Presidency College)
Aravindhan, S. (Department of Physics, Presidency College)
Publication Information
Journal of Integrative Natural Science / v.9, no.4, 2016 , pp. 255-260 More about this Journal
Abstract
The crystal structure of the saliciline derivatives N,N'-bis(3-chloro-2-methylsalicylidene)-1,4-butanediamine ($C_{20}H_{22}Cl_2N_2O_2$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the triclinic space group $P{\bar{i}}$ with unit cell dimension $a=4.6085(3){\AA}$, $b=5.9747(3){\AA}$ and $c=5.9747(3){\AA}$ [${\alpha}=83.889(4)^{\circ}$, ${\beta}=86.744(5)^{\circ}$ and ${\gamma}=82.085(5)^{\circ}$]. The title compound is essentially planar conformation. The compound lies across a crystallographic inversion centre and adopts E configurations with respect to the C-N bonds. The crystal packing of the molecules of compound is stabilized through weak O-H...N intra molecular interactions
Keywords
Chromene; Schiff Base Ligand; Single Crystal Structure; X-ray Diffraction;
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