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http://dx.doi.org/10.13160/ricns.2010.3.2.061

Dehydrogenative Polymerization of Hydrosilanes to Silicon Polymers  

Kim, Myoung-Hee (Nanotechnology Research Center and Department of Chemistry, Chonnam National University)
Lee, Jun (Nanotechnology Research Center and Department of Chemistry, Chonnam National University)
Mo, Soo-Yong (Nanotechnology Research Center and Department of Chemistry, Chonnam National University)
Kim, Jong-Hyun (Nanotechnology Research Center and Department of Chemistry, Chonnam National University)
Woo, Hee-Gweon (Nanotechnology Research Center and Department of Chemistry, Chonnam National University)
Publication Information
Journal of Integrative Natural Science / v.3, no.2, 2010 , pp. 61-71 More about this Journal
Abstract
Hydrosilanes possessing reactive Si-H bond are used in synthesizing various types of polysilanes by dehydrocoupling under the influence of various organometallic promoters. Catalytic Si-Si/Si-O coupling of hydrosilanes with hydrosilanes, alcohols, and lactones to silicon-based polymers are described in this article as selective examples of our recent research developments. These silicon-containing polymers can be used as a precursor to prepare useful functional materials for fabricating electronic devices.
Keywords
Polysilane; Dehydrocoupling; Hydrosilanes; Catalyst;
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