Browse > Article
http://dx.doi.org/10.7317/pk.2015.39.3.506

Cure Behavior and Tensile Properties of Ethylidene Norbornene/endo-Dicyclopentadiene Blends  

Jung, Jong Ki (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Choi, Jung Hwa (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Yang, Guang (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Park, Jongmoon (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Kim, Donghak (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Kim, Seonggil (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Lee, Jong Keun (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Oh, Myung-Hoon (Department of Materials Science and Engineering, Kumoh National Institute of Technology)
Kim, Bongsuk (Thinker Route Co., LTD, Gumi Electronics & Information Technology Research Institute)
Bang, Daesuk (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Publication Information
Polymer(Korea) / v.39, no.3, 2015 , pp. 506-513 More about this Journal
Abstract
Ethylidene norbornene (ENB) and its blends with endo-dicyclopentadiene (endo-DCPD) were prepared and reacted via the ring-opening metathesis polymerization (ROMP) reaction with the $1^{st}$ and $2^{nd}$ generation Grubbs' catalysts. Dynamic exothermic behaviors during ROMP and tensile properties after ROMP were evaluated using a differential scanning calorimeter (DSC) and a universal testing machine (UTM) for the samples, respectively. It revealed that the ROMP rate was accelerated with the less contents of endo-DCPD and under the $2^{nd}$ generation catalyst. Also, the addition of endo-DCPD and the $1^{st}$ generation catalyst resulted in higher tensile modulus and strength but lower toughness. Gel fraction measurement and fracture surface observation were made to understand the tensile properties.
Keywords
ethylidene norbornene; endo-dicyclopentadiene; blend; DSC; UTM;
Citations & Related Records
연도 인용수 순위
  • Reference
1 M. R. Buchmeiser, Chem. Rev., 100, 1565 (2000).   DOI   ScienceOn
2 M. Weck, J. J. Jackiw, R. R. Rossi, P. S. Weiss, and R. H. Grubbs, J. Am. Chem. Soc., 121, 4088 (1999).   DOI   ScienceOn
3 T. M. Trnka and R. H. Grubbs, Acc. Chem. Res., 34, 18 (2001).   DOI   ScienceOn
4 L. Matejka, C. Houtoman, and C. W. Macosko, J. Appl. Polym. Sci., 30, 2787 (1985).   DOI   ScienceOn
5 H. Ng, I. Manas-Zloczower, and M. Shmorhun, Polym. Eng. Sci., 34, 921 (1994).   DOI   ScienceOn
6 S. R. White, N. R. Sottos, P. H. Geubelle, J. S. Moore, M. R. Kessler, S. R. Sriram, E. N. Brown, and S. Viswanathan, Nature, 409, 794 (2001).   DOI   ScienceOn
7 T. A. Davidson and K. B. Wagener, J. Mol. Catal. A:Chem., 133, 67 (1998).   DOI
8 V. Dragutan, A. T. Balaban, and M. Dimonie, Olefin Metathesis and Ring Opening Polymerization of Cyclo-olefins, Wiley-Interscience, New York, 1985.
9 D. R. Kelsey, H. H. Chuah, R. H. Ellison, D. L. Handlin Jr, and B. M. Scardino, J. Polym. Sci., Part A: Polym. Chem., 35, 3049 (1997).   DOI
10 P. R. Khoury, J. D. Goddard, and W. Tam, Tetrahedron., 60, 8103 (2004).   DOI   ScienceOn
11 A. Bell, Catalysis in Polymer Synthesis, ACS Symp. Ser., American Chemical Society, Washington DC, 1992.
12 R. A. Fisher and R. H. Grubbs, Makromol. Chem.-Macromol. Symp., 63, 271 (1992).   DOI
13 K. J. Ivin and J. C. Mol, Olefin Metathesis and Metathesis Polymerization, Academic Press, San Diego, CA, 1997.
14 S. Hayano, H. Kurakata, Y. Tsunogae, Y. Nakayama, Y. Sato, and H. Yasuda, Macromolecules, 36, 7422 (2003).   DOI   ScienceOn
15 J. H. Oskam, H. H. Fox, K. B. Yap, D. H. McConville, R. O'Dell, B. J. Lichtenstein, and R. R. Schrock, J. Organometal. Chem., 459, 185 (1993).   DOI   ScienceOn
16 Y. Schrodi and R. L. Pederson, Aldrichim. Acta, 40, 45 (2007).
17 G. O. Wilson, K. A Porter, H. Weissman, S. R. White, N. R. Sottos, and J. S. Moore, Adv. Synth. Catal., 351, 1817 (2009).   DOI   ScienceOn
18 P. Schwab, R. H. Grubbs, and J. W. Ziller, J. Am. Chem. Soc., 118, 100 (1996).   DOI   ScienceOn
19 X. Liu, J. K. Lee, S. H. Yoon, and M. R. Kessler, J. Appl. Polym. Sci., 101, 1266 (2006).   DOI   ScienceOn
20 X. Sheng, J. K. Lee, and M. R. Kessler, Polymer, 50, 1264 (2009).   DOI   ScienceOn
21 J. K. Lee, X. Liu, S. H. Yoon, and M. R. Kessler, J. Polym. Sci., Part B: Polym. Phys., 45, 1771 (2007).
22 G. C. Huang, J. K. Lee, and M. R. Kessler, Macromol. Mater. Eng., 296, 965 (2011).   DOI   ScienceOn
23 A. S. Jones, J. D. Rule, J. S. Moore, S. R. White, and N. R. Sottos, Chem. Mater., 18, 1312 (2006).   DOI   ScienceOn
24 G. O. Wilson, M. M. Caruso, N. T. Reimer, S. R. White, N. R. Sottos, and J. S. Moore, Chem. Mater., 20, 3288 (2008).   DOI   ScienceOn
25 Y. Guang and J. K. Lee, Ind. Eng. Chem. Res., 53, 3001 (2014).   DOI   ScienceOn
26 E. F. Oleinik, Adv. Polym. Sci., 80, 49 (1986).   DOI
27 W. Jeong and M. R. Kessler, Carbon, 47, 2406 (2009).   DOI   ScienceOn