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http://dx.doi.org/10.7317/pk.2012.36.3.302

Plasma-Induced Grafting of Poly(N-vinyl-2-pyrrolidone) onto Polypropylene Surface  

Ji, Han-Sol (Department of Chemical Engineering, Chungnam National University)
Jung, Si-In (Department of Chemical Engineering, Chungnam National University)
Hur, Ho (Department of Chemical Engineering, Chungnam National University)
Choi, Ho-Suk (Department of Chemical Engineering, Chungnam National University)
Kim, Jae-Ha (Bioneer Co.)
Park, Han-Oh (Bioneer Co.)
Publication Information
Polymer(Korea) / v.36, no.3, 2012 , pp. 302-308 More about this Journal
Abstract
The objective of this study is to investigate optimum reaction conditions for the grafting of poly($N$-vinyl- 2-pyrrolidone) (PVP) onto the surface of plasma-treated polypropylene film. The plasma treatment conditions were fixed as 200 W rf power, 6 LPM Ar flow rate, 30 sec treatment time, and 5 min exposure time after treatment. For graft copolymerization, we investigated the change of grafting degree with respect to reaction time, reaction temperature and $N$-vinyl-2-pyrrolidone concentration. Maximum grafting degree was obtained at the conditions of 6 h reaction time, $90^{\circ}C$ reaction temperature, and 40% $N$-vinyl-2-pyrrolidone concentration. The introduction of PVP was confirmed by ATR-FTIR, XPS, and SEM analysis.
Keywords
plasma-induced graft copolymerization; poly(N-vinyl-2-pyrrolidone); polypropylene;
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