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Characterization of Acrylic Polymer-Grafted MWNTs Prepared by Atom Transfer Radical Polymerization  

Joo, Young-Tae (Department of Nano Systems Engineering, Center for Nano Manufacturing, Inje University)
Jung, Kwang-Ho (Department of Nano Systems Engineering, Center for Nano Manufacturing, Inje University)
Kim, Yang-Soo (Department of Nano Systems Engineering, Center for Nano Manufacturing, Inje University)
Publication Information
Polymer(Korea) / v.35, no.5, 2011 , pp. 395-401 More about this Journal
Abstract
MWNT/PMMA and MWNT/PDMAEMA nanocomposites were prepared using an atom transfer radical polymerization (ATRP). The FTIR and XRD analysis results showed that the nanocomposites were composed of MWNTs grafted by either PMMA(PMMA-g-MWNTs) or PDMAEMA(PDMAEMA-g-MWNTs). A controlled living radical polymerization of ATRP was characterized by the thermogram analysis for the nanocomposites. The morphologies of prepared nanocomposites were analyzed by transmission electron microscopy. Raman analysis results for the nanocomposites showed that there occurred covalent bonding between acrylic polymers and MWNTs.
Keywords
atom transfer radical polymerization; multi-walled carbon nanotube; PMMA; PDMAEMA; Raman spectroscopy;
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