Browse > Article

Resistive Humidity Sensor Using New N-Methacryloyl-N'-ethyl-N'-propyl Piperazinium Bromide Monomer and Their Properties  

Lee, In-Ho (Department of Chemistry and Department of Nanobiomedical Science, Dankook University)
Park, Chan-Kyo (Department of Applied Chemical Engineering, Dankook University)
Gong, Myoung-Seon (Department of Chemistry and Department of Nanobiomedical Science, Dankook University)
Publication Information
Polymer(Korea) / v.33, no.4, 2009 , pp. 326-332 More about this Journal
Abstract
New humidity-sensitive monomer, N-methacryloyl-N'-ethyl-N'-propyl piperazinium bromide (MANEPPB) was prepared by the quaternization reaction of N-methacryloyl-N'-ethyl piperazine (MANEP) with 1-bromopropane. Polyelectrolytes derived from the copolymers composed of MANEPPB/MMN/AA=60/35/5, 70/25/5, 80/15/5, 90/5/5 and 95/0/5 were prepared for the humidity-sensitive membranes, which were fabricated on the gold electrode by dipping method and were crosslinked by reacting copolymers with aziridine crosslinker, trimethylolpropane tris(2-methyl-1-aziridinopropionate) (TTAP). When the resistance dependences on the relative humidity of the sensors were measured, it was found that the resistance varied three orders of magnitude between 20 and 90%RH, which was satisfied with the requirement for the common humidity sensor operating at ambient humidity. Their hysteresis, temperature dependence, frequency dependence, response and recovery time and water durability were measured and evaluated as a humidity-sensing membrane.
Keywords
humidity sensor; methacrylamide; piperazinium bromide; aziridine crosslinker; water durability;
Citations & Related Records
Times Cited By KSCI : 4  (Citation Analysis)
Times Cited By Web Of Science : 4  (Related Records In Web of Science)
Times Cited By SCOPUS : 2
연도 인용수 순위
1 Y. Sakai, M. Matsuguchi, and T. Hurukawa, Sens. Actuat. B, 66, 135 (2001)   DOI   ScienceOn
2 D. G. Lee, Y. M. Jeon, and T. H. Lim, Polymer(Korea), 31, 194 (2007)   과학기술학회마을
3 D. G. Lee, Y. M. Jeon, and T. H. Lim, Polymer(Korea), 31, 302 (2007)   과학기술학회마을
4 C. W. Lee, H. W. Rhee, and M. S. Gong, Sens. Actuat. B, 73, 124 (2001)   DOI   ScienceOn
5 R. R. Roesler and K. Danielmeier, Prog. Org. Coat., 50, 1 (2004)   DOI   ScienceOn
6 M. S. Gong, J. S. Park, M. H. Lee, and H. W. Rhee, Sens. Actuat. B, 86, 20 (2002)   DOI   ScienceOn
7 M. Hijikigawa, S. Miyosh, T. Sugihara, and A. Jinda, Sens. Actuat., 4, 307 (1983)   DOI   ScienceOn
8 R. Rindone, WO 9,856,500 (1998)
9 Y. Sakai, Y. Sadaoka, M. Matsuguchi, and H. Sakai, Sens. Actuat. B, 25, 689 (1995)   DOI   ScienceOn
10 M. Matsuguchi, M. Shinmoto, Y. Sadaoka, T. Kuroiwa, and Y. Sakai, Sens. Actuat. B, 34, 349 (1996)   DOI   ScienceOn
11 C. W. Lee, B. K. Choi, and M. S. Gong, Analyst, 129, 651 (2004)   DOI   ScienceOn
12 S. H. Park, J. S. Park, C. W. Lee, and M. S. Gong, Sens. Actuat. B, 86, 68 (2002)   DOI   ScienceOn
13 Z. Yao and M. Yang, Sens. Actuat. B, 117, 93 (2006)   DOI   ScienceOn
14 C. W. Lee, H. S. Park, and M. S. Gong, Macromol. Res., 13, 96 (2005)   DOI   ScienceOn
15 Y. Li, Y. Chen, C. Zhang, T. Xue, and M. Yang, Sens. Actuat. B, 125, 131 (2007)   DOI   ScienceOn
16 C. W. Lee, H. S. Park, J. G. Kim, B. K. Choi, S. W. Joo, and M. S. Gong, Sens. Actuat. B, 109, 315 (2005)   DOI   ScienceOn
17 L. H. Gan, D. G. Roshan, X. J. Loh, and Y. Y. Loh, Polymer, 42, 65 (2001)   DOI   ScienceOn
18 Y. Li, M. J. Yang, and Y. She, Sens, Actuat. B, 107, 252 (2005)   DOI   ScienceOn
19 G. Chen and T. Univ. J. Appl. Polym. Sci., 63, 1609 (1997)   DOI   ScienceOn
20 N. B. Cho, T. H. Lim, Y. M. Jeon, and M. S. Gong, Macromol. Res., 16, 149 (2008)   DOI   ScienceOn
21 L. H. Gan, D. G. Roshan, X. J. Loh, and Y. Y. Loh, Eur. Polym. J., 34, 33 (1998)   DOI   ScienceOn
22 C. W. Lee, Y. Kim, S. W. Joo, and M. S. Gong, Sens. Actuat. B, 88, 21 (2003)   DOI   ScienceOn
23 M. S. Gong, M. H. Lee, and H. W. Rhee, Sens. Actuat. B, 73, 185 (2001)   DOI   ScienceOn
24 M. S. Gong, S. W. Joo, and B. K. Choi, Sens. Actuat. B, 86, 81 (2002)   DOI   ScienceOn
25 C. W. Lee, S. W. Joo, and M. S. Gong, Sens. Actuat. B, 105, 150 (2005)   DOI   ScienceOn
26 Y. Sakai, M. Matsuguchi, Y. Sadaoka, and Y. Hirayama, J. Electrochem. Soc., 140, 432 (1993)   DOI   ScienceOn
27 C. W. Lee, H. S. Park, and M. S. Gong, Sens. Actuat. B, 109, 256 (2005)   DOI   ScienceOn
28 Y. Sakai, Y. Sadaoka, and M. Matsuguchi, Sens. Actuat. B, 35, 85 (1996)   DOI   ScienceOn
29 M. Uedaa, K. Nakamura, K. Tanaka, H. Kita, and K. Okamoto, Sens. Actuat. B, 1`27, 463 (2007)   DOI   ScienceOn
30 S. Y. Son and M. S. Gong, Sens. Actuat. B, 86, 168 (2002)   DOI   ScienceOn
31 Y. Sakai, Y. Sadaoka, M. Matsuguchi, and K. Hirayama, International Conference on Solid-State Sensors and Actuators 1991(LA, USA), p 562 (1991)
32 X. Lv, Y. Li, L. Hong, D. Luo, and M. Yang, Sens. Actuat. B, 124, 347 (2007)   DOI   ScienceOn
33 http://www.shinyei.com
34 N. B. Cho, T. H. Lim, Y. M. Jeon, and M. S. Gong, Sens. Actuat. B, 130, 594 (2008)   DOI   ScienceOn