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Preparation of Silver/Polystyrene Beads via in Sito Reduction of Silver Alkylcarbamate Complex  

Lim, Tae-Ho (Department of Chemistry and Institute of Basic Science, Dankook University)
Jeon, Young-Min (Department of Chemistry and Institute of Basic Science, Dankook University)
Gong, Myoung-Seon (Department of Chemistry and Institute of Basic Science, Dankook University)
Publication Information
Polymer(Korea) / v.33, no.1, 2009 , pp. 33-38 More about this Journal
Abstract
Monodisperse polystyrene and its copolymer beads containing amine function were prepared for the electroless silver plating using reduction of silver alkylcarbamate complex in organic solvent. Soap-free emulsion polymerization was adopted for the polymerization of styrene, divinylbenzene (DVB), and 2-(N,N-dimethylamino) ethyl methacrylate (DAEMA) in the presence of poly (vinyl alcohol) in a water/methanol solvent. The resulting poly (styrene/DVB/DAEMA), containing 30/0$\sim$1.5/0$\sim$3 wt% in monomer composition, were found to be a sphere-type particle with diameter of 1 ${\mu}m$. Silver Ag-coated polystyrene beads were prepared by in sito reduction of a silver 2-ethylhexylcarbamate (Ag-EHCB) complex solution with hydrazine without pretreatment of polystyrene beads. Robust Ag/polystyrene beads were analyzed by SEM, UV -visible spectrometer and XRD.
Keywords
polystyrene bead, silver; silver alkylcarbamate complex; electroless plating;
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Times Cited By Web Of Science : 9  (Related Records In Web of Science)
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